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    The Shaky Life of a Droplet

    An evaporating drop of ouzo goes through several stages due to the interactions of oil, alcohol and water. If you turn the situation around by placing a drop of (blue-dyed) water in a mixture of alcohol and anise oil (top image), you get some similarly odd behavior. The drop of water shimmies and grows as alcohol dissolves into it, carrying the occasional oil droplet with it. Eventually, the droplet grows large enough and buoyant enough that part of it detaches and floats to the surface (middle image). If you increase the alcohol ratio in the surrounding fluid, you speed up this process, causing droplets to stream up to the surface (bottom image). (Image and video credit: O. Enriquez et al., source)

  • The Color of Droplets

    The Color of Droplets

    In nature, color comes from many sources: like the pigmentation of skin and hair, the structural iridescence of a butterfly’s wings, or the refraction of a rainbow from water droplets. Recently, scientists discovered another source of brilliant color in simple, hemispherical water droplets.

    When small droplets form on a transparent surface, they form concave shapes capable of total internal reflection. This means that two light rays entering from the same angle can follow different paths inside the droplet. After reflecting several times, the light rays exit the droplet with a phase difference and how large that phase difference is determines the color. Check out the video below for some brightly colored examples of the effect. The researchers hope the technique will eventually be suitable for creating dye-free, color-changing technologies. (Image credit: F. Frankel; video credit: MIT News; research credit: A. Goodling et al.)

  • Water Impacts

    Water Impacts

    In the clean and simplified world of the laboratory, a droplet’s impact on water is symmetric. From a central point of impact, it sends out a ring of ripples, or even a crown splash, if it has enough momentum. But the real world is rarely so simple.

    Here we see how droplets impact when the wind is blowing against them. The drops fall at an angle, creating an oblique cavity. Rings of ripples spread from the impact, but the ligaments of a splash crown form only on the leeward side. As the wind speed increases, so does the violence of the impact, eventually beginning to trap tiny pockets of air beneath the surface. Those miniature bubbles can spray droplets and aerosols into the air when they finally pop. (Image and video credit: A. Wang et al.)

  • Moving Droplets

    Moving Droplets

    Microfluidic devices – such as those used by individuals with diabetes to monitor their blood glucose levels – are all about transport. Typically, these devices use some kind of externally applied force, like a temperature gradient or electrical field, to force liquids through the device’s narrow channels. But a new study describes a way to move droplets without an external force.

    The researchers built their devices using two slips of glass, coated with an oil-attracting, water-repellent mixture. They attached the glass slips with a narrow spacer at one end, leaving the other end free. This made a narrow, but slightly flexible gap. When the scientists placed an oil drop inside the closed end, it spread on the glass, pulling the two sides closer to one another. Water drops, on the other hand, tried to force the walls apart, in an effort to minimize contact. Both sets of drops, interestingly, moved toward the open end of the device.

    The researchers found that the shapes assumed by the droplets create an internal pressure gradient, which, in both cases, slowly moves the drops. They call this method bendotaxis, a type of self-propulsion driven by the drops’ ability to bend the material they’re touching. It’s not a fast way to transport fluids – the drops moved only a few micrometers per second – but it may be useful for applications like drug deliveries where the liquid needs to be administered slowly over a longer period. (Image credit: TesaPhotography; research credit: A. Bradley et al.; via APS Physics; submitted by Kam-Yung Soh)

  • Growing Droplets

    Growing Droplets

    The moisture in clouds eventually condenses into droplets that grow into raindrops and fall. Some steps in this process are well understood, but others are not. In particular, scientists have struggled with the problem of how droplets grow from about 30 microns to 80 microns, where they’re big enough to start falling and merging.

    Laboratory experiments and numerical simulations (below) have shown that turbulence can help drive small water drops together. When droplets are tiny and light, they simply follow the air flow. But when they’re a little heavier, turbulent eddies (seen in orange below) act like miniature centrifuges, flinging larger water droplets (shown in cyan below) out into clusters, where they’re more likely to collide with one another.

    Although this effect has been seen in experiments and simulation, it’s been difficult to capture in clouds themselves. But a new set of test flights (above) confirms that this mechanism is present in the wild as well! (Image credit: UCAR/NCAR Earth Observing Laboratory, P. Ireland et al., source; research credits: M. Larsen et al., P. Ireland et al.; via APS Physics; submitted by Kam-Yung Soh)

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  • Spinning Droplet Galaxies

    Spinning Droplet Galaxies

    Water flung from a spinning tennis ball takes on a shape reminiscent of a spiral galaxy. As it detaches, water leaves the surface with both the tangential velocity of the spinning ball and a radial velocity due to the centrifugal force flinging it. The continued spin of the ball makes the thin ligaments of water still attached to it spiral and stretch. Eventually, surface tension can no longer hold the water together against the centrifugal forces, and the ligaments split into a spray of droplets. (Image credit: W. Derryberry and K. Tierney)

  • Nestling Droplets

    Nestling Droplets

    Pay attention after a rainfall, and you may notice beads of water gathering in the corners of a spider’s web or along the leaves of a cypress tree (bottom right). Look closely and you’ll notice that the largest droplets don’t form along a straight fiber. Instead they nestle into the corners of a bent fiber (top image). Researchers recently characterized this corner mechanism and found that the angle at which the largest droplets form is about 36 degrees. This angle provides the optimal conditions for capillary action and surface tension to hold large drops in place. At smaller angles, a growing droplet’s weight pulls it down until the thin film holding the droplet near the top ruptures and the droplet falls. At larger angles, a heavy droplet will slowly detach from one side of its fiber and shift toward the other side until its weight is too great for the wetted length of fiber to hold. Then it detaches completely and falls. (Research and image credit: Z. Pan et al.; via T. Truscott)

  • Wrapping Droplets

    Wrapping Droplets

    Future efforts for targeted drug delivery may require encapsulating droplets before transporting them to their final location. One method for encapsulation is wrapping a drop in a thin, solid sheet. Previously, we saw that drops can wrap themselves with a little outside assistance, but here the drops achieve that same feat on their own, using the energy of droplet impact to wrap liquids. 

    Here’s how it works: float a thin sheet on a bath of a liquid like water, then let an oil drop fall into the bath. Its impact deforms the air-water interface and, with a sufficiently energetic impact, causes the oil droplet to pinch off. The flexible sheet wraps around the droplet, and the encapsulated droplet sinks due to gravity. The shape of the final drop depends on the sheet’s initial geometry. The researchers have successfully used circular, triangular, and cross-shaped sheets to wrap droplets. Check out the original paper or the video below for more. (Image and research credit: D. Kumar et al.; video credit: Science)

  • Water Atop Oil

    Water Atop Oil

    At first glance, this image looks much like the impact of any drop on a pool of the same liquid, but that’s not what you’re seeing. This is the impact of a water droplet on a thin film of oil, and the immiscibility of those two fluids has important effects on the collision. When the water drop impacts, it spreads and forms a compound crown that rises out of the fluid. Eventually, that momentum runs out and the crown falls into the liquid.

    Water’s intermolecular forces are strong enough to pull the remains of the droplet back in on itself. As that fluid collides at the center, it gets forced up into a central jet with enough energy to eject a droplet or two at its tip. Even though this looks like a Worthington jet, it’s not. Worthington jets form after the collapse of a cavity in the impacted liquid – in other words, they form on pools, not on films. Despite the visual similarity, this central jet is formed entirely differently! (Image and research credit: Z. Che and O. Matar, source; submitted by O. Matar)

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    Jumping Droplets

    Condensation, which removes heat by changing a vapor into a liquid, is a common feature in industrial heat transfer. When droplets form on surfaces, they typically have to grow to millimeter size before gravity causes them to slide off and open up the surface to new droplet formation. Hydrophobic surfaces can shed droplets a little sooner. Droplets only 100 micrometers in size will spontaneously jump off hydrophobic surfaces due to the release of excess surface energy during droplet coalescence, but this only happens when those droplets have a small contact area with the surface. Defects in the nanoscale structure of the surface can allow water to squeeze in between posts and hold on.

    To counter this, new experiments packed copper nanowires into a dense 3D array. This permits fewer defects and helps condensing droplets leap from the surface sooner. Each droplet carries away a bit of the surface’s heat. The new method is impressively efficient at it. Researchers found the new heat exchanger could remove 100% more heat than previous hydrophobic designs. (Video credit: Science; research credit: R. Wen et al.)

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