When a drop settles gently against a pool of the same liquid, it will coalesce. The process is not always a complete one, though; sometimes a smaller droplet breaks away and remains behind (to eventually do its own settling and coalescence). When this happens, it’s known as partial coalescence.
Here, researchers investigate ways to tune partial coalescence, specifically to produce more than a single droplet. To do so, they add surfactants to the oil layer surrounding their water droplet. The surfactants make the rebounding column of water skinnier, which triggers the Rayleigh-Plateau instability that’s necessary to break the column into more than one droplet. (Image and video credit: T. Dong and P. Angeli)
Seawater froths and foams in ways that freshwater rarely does. A new study pinpoints the ocean’s electrolytes as the reason bubbles resist merging there. By studying the final moments before bubbles coalesce in both pure and salt water, researchers found that dissolved salts slow down the drainage of the thin film of liquid between two bubbles. Once the film reaches a 30-50 nanometer thickness, its electrolyte concentration causes a difference in surface tension that slows the outward flow of liquid in the film. That keeps the film in place longer and makes bubbles form foams instead of merging or popping. (Image credit: P. Kuzovkova; research credit: B. Liu et al.; via APS Physics)
Soft colors and sudden coalescence combine in this short film from Susi Sie’s team. The visuals rely on liquid lenses (likely oil) floating atop a water bath. You can see how the fluids get manipulated in their behind-the-scenes video, which also provides a peek at how the sound effects get made. (Video credit: S. Sie et al.)
Saturn’s moon Titan is a fascinating foil to our planet. It’s the only other body in our solar system with liquid bodies — lakes and seas — on its surface. But where Earth’s oceans are filled with water, Titan’s frigid lakes are liquid hydrocarbons. This video, “Titan,” is a short film inspired by the moon’s seas and is made up of various liquids and chemical reactions filmed under magnification. Sit back and enjoy the flow! (Image and video credit: S. Bocci/Julia Set Lab)
As oil slides down two slowly converging wires, the droplets will merge into a sheet that stretches between both wires. When this happens can vary somewhat but occurs somewhere around the liquid’s capillary length.
In the poster above, the leftmost image (not the illustration) shows three possible merger points. To the right of the image, is a teal curve; this is a probability density function. Essentially, this curve shows where the merger is most likely to occur. The peak of the curve corresponds to the most probable point of merger.
The following two composite images show the same system — same oil flow rate, same wire spacing — with gas blowing upward along the wires. As the gas’s flow rate increase, the oil drops get larger, making the oil films thinner. The result? The wires have to get closer to one another before the oil merges. That’s reflected in the yellow and orange probability density functions, which have peaks further along the wires than the no-gas-flow case. (Image credit: C. Wagstaff et al.)
When droplets coalesce, they perform a wiggly dance, gyrating as the capillary waves on their surface interfere. When the droplets have matching surface tensions, like the two water droplets in the animation on the lower left, the coalescence dance is symmetric. But for differing droplets, like the water and ethanol droplets merging on the lower right, coalescence is decidedly asymmetric.
Two water droplets merge symmetrically.A water droplet and an ethanol droplet merge asymmetrically.
The asymmetry arises from the droplets’ different surface tensions. The size and speed of the capillary waves that form on a droplet depend on surface tension, so droplets of different liquids have inherently different capillary waves. During merger, the interference of these capillary waves causes the asymmetry we see. (Image credit: top – enfantnocta, coalescence – M. Hack et al.; research credit: M. Hack et al.)
Droplets can skitter across a hot surface on a layer of their own vapor, thanks to the Leidenfrost effect. If two Leidenfrost droplets of the same liquid collide, they merge immediately. But that doesn’t always happen with two dissimilar liquids. A new study looks at how dissimilar Leidenfrost droplets collide. The researchers found that these drops can bounce off one another repeatedly before their eventual merger (Image 1).
Just as a vapor layer prevents the drops from touching the hot plate, a vapor layer forms between them when they collide, preventing contact (Image 2). Because of these three distinct areas of Leidenfrost vapor (one beneath each drop and one between the drops), the researchers call this the triple Leidenfrost effect.
Eventually, the more volatile (in other words, easily evaporated) drop shrinks to a size similar to its capillary length, at which point the drops merge. If the boiling points of the two liquids are vastly different, the merger can be explosive (Image 3). (Image and research credit: F. Pacheco-Vázquez et al.; via APS Physics)
How does a droplet sinking through an immiscible liquid settle onto a surface? Conventional wisdom suggests that the settling drop will slowly squeeze the ambient fluid film out of the way, form a liquid bridge to the solid beneath, and spread onto the surface. But for some droplets, that’s not how it goes.
While watching a glycerol droplet settle through silicone oil, researchers discovered a new mechanism for wetting. Initially, the silicone oil drained from beneath the drop, as expected. But then the thinning of the film stalled. Tiny bright spots (above) appeared beneath the light and dark interference fringes of the parent drop. These are spots of glycerol, formed when material from the main drop dissolved into the oil and then nucleated onto the solid surface below. Over time, the island-like spots of glycerol grew. Eventually one grew large enough to coalesce with its parent drop (below), causing the glycerol to quickly spread over the solid surface!
Islands of liquid (darker rings) grow beneath a parent drop (brighter rings) until reaching a size where they coalesce, causing the interference fringes to disappear.
The key to this phenomenon seems to be that immiscibility isn’t perfect. Even trace amounts of solubility between the drop and surrounding fluid are enough to allow these islands to form. And once formed, the islands will grow as long as the drop fluid and the solid surface are chemically attractive. (Image, research, and submission credit: S. Borkar and A. Ramachandran; see also Nature Behind the Paper)
Shifting bubbles and psychedelic colors abound in this abstract video from artist Rus Khasanov. He provides no specifics as to the materials he uses for this video, but my guess is they likely include oil, soap, and polarizing filters. It’s a fun and funky video! See more of Khasanov’s work on his website and Instagram. (Image and video credit: R. Khasanov)
Liquids flowing down a fiber can form bead-like droplets that may sit symmetrically (a) or asymmetrically (b) on the fiber. In general, the asymmetric droplets appear as surface tension increases or as the fiber diameter increases. The pattern of the droplets changes with flow rate. Within each subfigure, the flow rate increases from left to right. At low flow rates, we see only one or two large droplets migrating down the fiber. At moderate flow rates, a regular pattern of drops emerges. And at high flow rates, droplets coalesce on the fiber to form drops large enough that they fall and sweep up the downstream droplets. (Image and research credit: C. Gabbard and J. Bostwick)
