FYFD

Tag: encapsulation

  • Encapsulating Drops

    Encapsulating Drops

    Sometimes a droplet needs a little protection while it’s traveling to its destination. When that’s the case, we often try to encapsulate it in a layer of material that won’t be affected by whatever environment the drop is traveling through. In this study, researchers aimed to give their drops not one but two layers of protection — in as simple a way as possible.

    The team began with three layers of liquid. The lowest layer was water, the middle layer was an oil, and the top layer was a mixture of water and isopropyl alcohol. Next, they added glass particles that were denser than the alcohol, but less dense than the oil. This caused the particles to form a clump — a granular raft — along the interface between the alcohol and the oil (not shown). When the layer of particles became heavy enough, it began to sink into the oil, carrying some of the alcohol with them. This conglomeration formed the initial droplet of alcohol mixture encased in an armor of glass beads.

    As this armored droplet sank, it approached the second interface: the oil-water interface. At this juncture, the team observed three different outcomes. When the glass particles were small or light, the armored drop would come to a rest at the oil-water interface. As the drop deformed, water would pierce the armor, causing the whole drop to rupture (Image 1).

    In the second case, heavier particles caused the armored drop to sink through the oil-water interface, but a low oil viscosity meant that the oil film drained from the bottom of the drop before the drop was fully encapsulated. Once again, this let the water through and ruptured the droplet (Image 2).

    In the final case, armored drops with just the right bead density and oil viscosity would sink through the oil-water interface until the oil pinched off behind the drop. This pinch-off allowed the oil to redistribute around the drop, encapsulating it in layers of both oil and particles, thereby protecting it as it continued its journey (Image 3). (Image credits: top – Girl with red hat, experiment – A. Hooshanginejad et al.; research credit: A. Hooshanginejad et al.)

  • Wrapping Droplets

    Wrapping Droplets

    Future efforts for targeted drug delivery may require encapsulating droplets before transporting them to their final location. One method for encapsulation is wrapping a drop in a thin, solid sheet. Previously, we saw that drops can wrap themselves with a little outside assistance, but here the drops achieve that same feat on their own, using the energy of droplet impact to wrap liquids. 

    Here’s how it works: float a thin sheet on a bath of a liquid like water, then let an oil drop fall into the bath. Its impact deforms the air-water interface and, with a sufficiently energetic impact, causes the oil droplet to pinch off. The flexible sheet wraps around the droplet, and the encapsulated droplet sinks due to gravity. The shape of the final drop depends on the sheet’s initial geometry. The researchers have successfully used circular, triangular, and cross-shaped sheets to wrap droplets. Check out the original paper or the video below for more. (Image and research credit: D. Kumar et al.; video credit: Science)

  • Self-Wrapping Drops

    Self-Wrapping Drops

    A liquid drop can fold itself up in a thin sheet. The animation above shows a drop of water with an ultra-thin (79nm) circular sheet of polystyrene atop it. As a needle removes water from the underside of the droplet, the shrinking droplet causes wrinkles and folds to form in the sheet. What’s going on here is a competition between the energy required to change the droplet’s shape and the energy needed to bend the sheet. Eventually, the droplet’s volume is small enough that the bending of the sheet overrules surface tension in dictating the droplet’s shape. The result is a tiny empanada-shaped droplet completely encapsulated by the sheet. (Image credit: J. Paulsen et al., source; research paper)

  • Encapsulating Drops

    Encapsulating Drops

    Building and manipulating drops containing multiple chemicals is useful in pharmaceutical applications. But it can be a challenge to encapsulate multiple fluids without mixing them immediately. The research poster above describes a clever and simple method of building these compound drops. It uses a crosswise array of fibers, as seen in the top image. Dyed water droplets are placed at each intersection, pinning them in place. Then a larger drop of oil is added to the vertical fiber. As it runs down the fiber, it collects and encapsulates the individual droplets, creating the compound drop seen in the bottom photo. (Photo credit: F. Weyer et al.)