FYFD

Tag: evaporation

  • Soap Film Evolution

    Soap Film Evolution

    The beautiful colors of a soap film reflect its variations in thickness. As a film drains and evaporates, it turns to shades of gray and black as it gets thinner. More than fifty years ago, one scientist proposed a free-energy-based explanation for how such ultrathin films might evolve. But it’s taken another half a century for experimental techniques to reach a point where the thickness of these ultrathin films could be measured well enough to test that theory. The new mechanism, known as spinodal stratification, has been observed in both vertical films (top) and foam (bottom) but has so far not been observed in any horizontal configuration, suggesting that buoyant effects are likely important, too. (Image and research credit: S. Yilixiati et al.; submitted by James S.)

  • Keeping Bubbles Around

    Keeping Bubbles Around

    Bubbles don’t stick around in pure water. Surfactants are needed to stabilize the thin liquid film for longer than the blink of an eye. But that’s not necessarily the case for other liquids. As the video below shows, a bubble in isopropyl alcohol is quite stable. This is because of the alcohol’s volatility – its ability to evaporate easily.

    As the alcohol in the bubble film evaporates, it cools the film, creating a difference in surface tension that pulls fresh alcohol up into the bubble film. It’s so efficient at pulling alcohol up that the alcohol can’t evaporate fast enough to use it all. Once the excess alcohol is heavy enough, it slides back down the side of the bubble. Overall, though, the process is enough to keep a bubble in pure isopropyl alcohol from rupturing for minutes to hours at a time. (Image and video credit: M. Menesses et al.)

  • Exploding a Drop

    Exploding a Drop

    Leidenfrost drops levitate over a hot substrate on a thin layer of their own vapor, constantly replenished as the drop evaporates. For the most part, previous studies have focused on pure droplets, but a new one looks at what happens when you add surfactants – and the results are, well, explosive.

    Surfactants are a type of chemical that like to gather at the surface of a drop, and, unlike water, they’re nonvolatile – they don’t evaporate easily. So as the Leidenfrost drop evaporates and shrinks, the surface of the drop becomes more and more crowded with surfactant molecules. Eventually, they form an elastic shell around the remaining water, making evaporation more difficult.

    Inside the droplet, the temperature continues to rise, eventually reaching a point where bubbles of vapor can nucleate inside. When that happens, the bubbles expand almost instantaneously and the internal pressure spike bursts the shell, causing the entire droplet to explode. (Image and research credit: F. Moreau et al.)

  • An Inverted Leidenfrost Drop

    An Inverted Leidenfrost Drop

    Leidenfrost drops – liquid drops that levitate on a layer of their own vapor over a hot surface – have been all the rage in recent years. We’ve seen how they can be guided, trapped, and self-propelled. What you see here is a bit different. This is a droplet of room-temperature ethanol deposited on a bath of liquid nitrogen. What levitates the droplet in this case is vaporous nitrogen evaporating from the bath.

    The droplet is quickly cooling down; it freezes after its second or third bounce off the side walls of the beaker. What causes the droplet to self-propel is an asymmetry of the thin vapor layer beneath the droplet. As soon as some instability causes a slight difference in the thickness of the vapor layer, that triggers the propulsion, which the drop maintains even after freezing. (Image and research credit: A. Gauthier et al.)

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    The Clever Cat’s Tongue

    Cats spend almost a quarter of their waking hours grooming, and their tongues are wonderfully specialized for this task, allowing them to clean, cool, and untangle themselves with ease. Anyone who’s ever been licked by a cat knows their tongues feel sandpaper-y. This is due to rear-facing hook-like structures called papillae that have a stiffness comparable to human fingernails.

    The papillae are hollow, and their U-shaped tip helps them wick up saliva, which the cat deposits deep into its undercoat when it licks. Although the papillae only hold about 5% of the volume of saliva on the cat’s tongue, this wicking action is key because most of the tongue surface can’t reach the inner coat; only the papillae do. The saliva that reaches these dense inner hairs is important not only for cleaning the fur, but for helping the cat cool off. As the saliva evaporates, it carries heat away with it, just like sweating does for us.

    The papillae are key to untangling fur, but their shape also makes it easy to remove hairs caught on the tongue. Researchers built a 3D-printed cat-inspired hair brush to show how efficient and easy to clean a cat’s tongue can be! (Video credit: Science; research credit: A. Noel and D. Hu)

  • What Drives Droplets

    What Drives Droplets

    There’s been a lot of interest recently in what goes on inside droplets made up of more than one fluid as they evaporate. This can be entertaining with liquids like whiskey or ouzo, but it has practical applications in ink-jet printing and manufacturing as well. And a new experiment suggests that we’ve been fundamentally wrong about what drives the flow inside these drops.

    As these drops evaporate, a donut-shaped recirculating vortex forms inside them, as seem in the cutaway views above. Conventional wisdom says that vortex is driven by surface tension. Evaporation of components like alcohol is more efficient at the edges of the drop, and as the alcohol evaporates, it creates a higher surface tension at the drop’s edge than at its peak. Marangoni forces then pull fluid down toward the edges, creating the vortex. That explanation is  consistent with observations of a sessile drop sitting on top of a surface (left side of images).

    But those observations are also consistent with another explanation: evaporating ethanol makes the local density higher, so alcohol-rich parts of the drop rise toward the peak while alcohol-poor regions sink. This difference in density would also create a flow pattern consistent with observations. So which is the real driver, surface tension or gravity?

    To find out, researchers flipped the drop upside-down (right side of images). When hanging, the preferred flow direction due to surface tension doesn’t change; flow should still go from the deepest point on the drop toward the edge. But gravity is swapped; alcohol-rich areas should be found near the edge and attachment points of the drop because buoyancy drives them there. And that is exactly what’s observed. The flow direction inside the hanging droplet is consistent with the direction prescribed by buoyancy-driven flow, thereby upending conventional wisdom. It turns out that gravity, not surface tension, is the major driver of internal flow in these multi-component droplets! (Image and research credit: A. Edwards et al.; via APS Physics; submitted by Kam-Yung Soh)

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    Rivers in the Sky

    The water cycle is quite a bit more complicated than what we learn in elementary school, and the environment around us contributes to that cycle in invisible but vital ways. In this video, Joe Hanson of It’s Okay to Be Smart pulls back the veil on this in the context of the Amazon river basin and how the Amazon rainforest itself creates an atmospheric river that carries more water than its namesake river.

    Trees release water into the air almost constantly as they transpire. And to trigger that water to fall as rain, trees can release other compounds that serve as a nucleus around which raindrops can form. The condensing raindrops form clouds, which lower the air pressure and create winds, thereby creating an atmospheric river flowing from the Atlantic back up the Amazon River. That stream carries rain that feeds the rainforest and the Amazon River, continuing the cycle. (Video and image credit: It’s Okay to Be Smart)

  • Wheeling Drops

    Wheeling Drops

    Leidenfrost drops – which skitter almost frictionlessly across extremely hot surfaces on a thin layer of their own vapor – are notoriously mobile. We’ve seen numerous methods of controlling their propulsion, often using specially-shaped surfaces. But it turns out that some Leidenfrost drops can self-propel even on a smooth, flat surface (top image). 

    Internally, large Leidenfrost drops have complicated, but symmetric flows that are driven by temperature and surface tension variations across the drop. But as the drop evaporates, that symmetry eventually gets broken, leaving behind a single large circulating flow. 

    Beneath the drop, that internal circulation affects the vapor layer. It causes the layer to take on an overall tilt, and the rotation, along with that slight angle in the vapor layer, causes the Leidenfrost drop to roll away like a wheel. (Image and research credit: A. Bouillant et al.; via NYTimes)

  • Convection Without Heat

    Convection Without Heat

    We typically think of convection in terms of temperature differences, but the real driver is density. In the animations above, cream sitting atop a liqueur is undergoing solutal convection – no temperature difference needed! The alcohol in the liqueur mixes with the cream to form a lighter mixture that rises to the surface. The lower surface tension of the alcohol is also good at breaking up the cream, forming little cells. As the alcohol in those cells evaporates, the cream gets heavier and sinks down into the liqueur, where it can pick up more alcohol, rise back to the surface, and begin the cycle again. (Image credit: J. Monahan et al., source)

  • Surfaces That Scrape Off Ice

    Surfaces That Scrape Off Ice

    Ice can be a terrible pest, freezing to surfaces like roads and airplane wings and causing all sorts of havoc. Some surfaces, though, can actually prompt a freezing drop to scrape itself off. There are a couple key effects in play here. The first is that the surface is nanotextured – in other words, it has extremely small structures on its surface. This makes it hydrophobic, or water-repellent. The second key ingredient is that the drop is cooling evaporatively; that means heat is escaping along the air-water interface instead of conducting through the solid surface. As a result, the freezing front forms at the interface and pushes inward. Water expands as it freezes, which tries to force the interior liquid out, toward the bottom of the drop. On a normal surface, this would force the contact line – where air, water, and surface meet – to push outward. But the nanotexture of the hydrophobic surface pins that line in place. So the expanding ice pushes the frozen drop upward, scraping it off the surface! (Video and image credit: G. Graeber et al., source)