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    Reader Question: Non-Coalescing Droplets

    Reader ancientavian asks:

    I’ve often noticed that, when water splashes (especially as with raindrops or other forms of spray), often it appears that small droplets of water skitter off on top of the larger surface before rejoining the main body. Is this an actual phenomenon, or an optical illusion? What causes it?

    That’s a great observation, and it’s a real-world example of some of the physics we’ve talked about before. When a drop hits a pool, it rebounds in a little pillar called a Worthington jet and often ejects a smaller droplet. This droplet, thanks to its lower inertia, can bounce off the surface. If we slow things way down and look closely at that drop, we’ll see that it can even sit briefly on the surface before all the air beneath it drains away and it coalesces with the pool below. But that kind of coalescence cascade typically happens in microseconds, far too fast for the human eye.

    But it is possible outside the lab to find instances where this effect lasts long enough for the eye to catch. Take a look at this video. Here Destin of Smarter Every Day captures some great footage of water droplets skittering across a pool. They last long enough to be visible to the naked eye. What’s happening here is the same as the situation we described before, except that the water surface is essentially vibrating! The impacts of all the multitude of droplets create ripples that undulate the water’s surface continuously. As a result, air gets injected beneath the droplets and they skate along above the surface for longer than they would if the water were still. (Video credit: SuperSloMoVideos)

  • Dye Droplet

    Dye Droplet

    A drop of fluorescent dye falling into quiescent water forms fantastical structures that are a mixture of vorticity, turbulence, and molecular diffusion. The horseshoe-like shape near the front of the drop is a typical shape for two fluids strained by moving past one another. The main section of the drop billows outward like a parachute, but the turbulence of its wake stretches the dye into fine threads that quickly disperse in the water. (Photo credit: D. Quinn et al.)

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    “Levitating Water”

    Al Seckel, a cognitive neuroscientist and expert on illusions, created this “Levitating Water” installation, in which multiple streams of water appear as a series of levitating droplets thanks to a strobing light. The well-timed strobe lighting tricks the brain into seeing many different falling droplets as the same, nearly stationary droplet. The effect is similar to the one created by vibrating a stream of falling water. (Video credit: wunhanglo)

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    Droplet Bounce

    This high-speed video shows the remarkable resilience of a water droplet upon impact against as a solid surface. The droplet deforms into a pancake-shape, with its center depressing almost flat before rebounding upward. The rest of the drop follows, splitting into several droplets as capillary waves dance across its surface. When one satellite drop almost escapes, the main droplet just barely comes in contact with it, the coalescence enough to tip surface tension into pulling them together instead of breaking them apart.  (Video credit: K. Suh/ChemistryWorldUK)

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    Breaking into Droplets

    A falling column of liquid, like the water from your faucet, will tend to break up into a series of droplets due to the Plateau-Rayleigh instability. This instability is driven by surface tension. Small variations in the radius of the column occur naturally. Where the radius shrinks, the pressure due to surface tension increases, causing liquid to flow away, which shrinks the column’s radius even further. Eventually the column pinches off and breaks into droplets. What’s especially neat is that the size of the final droplets can be predicted based on the column’s initial radius and the wavelength of its disturbances. (Video credit: BYU Splash Lab)

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    Encapsulating Droplets

    In applications like drug delivery, it’s often desirable to encapsulate one or more liquid droplets in an additional immiscible fluid. These drops-within-drops, called double emulsions, are typically a multi-step process, created from the innermost drop outward. In this new microfluidic technique, though, researchers are able to create multi-component emulsions in a single step. A double-bored capillary tube creates the two inner droplets (both water, dyed different colors) while oil flows down the outside of the injection tube to encapsulate the droplets. The multi-component double emulsions then flow as one to the right in the outer carrier fluid. The spacing of the capillary tubes is critical to prevent the inner droplets from coalescing with one another. (Video credit: L. L. A. Adams et al.)

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    Shocking Droplets

    Typical liquid drops will break apart into long, stretched ligaments and a spray of tiny droplets when deformed. But with just a small addition of polymers, these same liquids become viscoelastic and capable of some pretty incredible behaviors. This video shows a viscoelastic drop being struck by a shock wave that passes from right to left. The droplet is smashed and deformed, then stretches into jellyfish-like sheet of liquid. But incredibly, the elastic forces in the droplet are enough to hold it together. Researchers are interested in understanding these behaviors for many applications, including preventing accidental explosions caused by explosive fuels atomizing in air. (Video credit: T. Theofanous et al.)

  • Bouncing to Mix Oil and Water

    Bouncing to Mix Oil and Water

    Mixing immiscible liquids–like oil and water–is tough. The best one can usually do is create an emulsion, in which droplets of one fluid are suspended in another. The series of images above shows a double emulsion consisting of oil and water that’s been formed by bouncing the compound droplet on a vibrating bath. The vibration of the liquid surface keeps the droplet from coalescing with the bath and the deformation provides mixing. The top row shows the initial impact while the bottom row of images shows the droplet after many bounces. As time goes on, the layer of oil around the compound drop becomes a cluster of tiny droplets contained within the water portion of the drop. (Photo credit: D. Terwagne et al.)

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    Skittering Droplets

    Water splattered onto a a hot skillet will skitter and skip across the surface on a thin layer of vapor due to the Leidenfrost effect. The partial vaporization of the droplet provides a low-friction cushion for the droplet to glide on and acts as an insulating layer that delays the vaporization of the rest of the droplet. Modernist Cuisine shows us how serene this common and sometimes explosive effect looks at 3,000 frames per second. (On the topic of cooking, you can use the Leidenfrost effect to see if your skillet is hot enough when making pancakes. If a few droplets of water skitter across the pan before sizzling away, then your pan is ready for batter!) (Video credit: Modernist Cuisine; submitted by Eban B.)

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    Making Metal Water-Repellent

    Chemical treatments can be used to render metals hydrophobic, causing water to bead on the surface rather than spreading to wet it. Treating the surface by immersing it in boiling water before applying the chemicals creates a nanoscale texture that accentuates the hydrophobicity. Even on a common metal like aluminum, this combination of texturing and chemical treatment leads to superhydrophobic behavior. Here the technique is demonstrated by spraying water droplets on a piece of treated aluminum. (Video credit: B. Rosenberg et al.; submitted by D. Quinn)

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