What goes on inside an evaporating droplet made up of more than one fluid? This is a perennially fascinating question with lots of permutations. In this one, researchers observed water-poor spots forming around the edges of an evaporating drop, almost as if the two chemicals within the drop are physically separating from one another (scientifically speaking, “undergoing phase separation“). To find out if this was really the case, they put particles into the drop and observed their behavior as the drop evaporated. What they found is that this is a flow behavior, not a phase one. The high concentration of hexanediol near the edge of the drop changes the value of surface tension between the center and edge of the drop. And that change is non-monotonic, meaning that there’s a minimum in the surface tension partway along the drop’s radius. That surface tension minimum is what creates the separated regions of flow. (Video and image credit: P. Dekker et al.; research pre-print: C. Diddens et al.)
Tag: droplets

Within a Drop
In this macro video, various chemical reactions swirl inside a single dangling droplet. Despite its tiny size, quite a lot can go on in a drop like this. Both the injection of chemicals and the chemical reactions themselves can cause the flows we see here. Surface tension variations and capillary waves on the exterior of the drop can play a role, too. Just because a flow is tiny doesn’t mean it’s simple. (Video and image credit: B. Pleyer; via Nikon Small World in Motion)

Chemical reactions swirl within a single, hanging droplet. 
“Paradolia”
In “Paradolia,” filmmaker Susi Sie plays with pareidolia, our tendency to seek patterns in nebulous data — like faces on a slice of toast. Droplets of miscible and immiscible fluids collide, part, and mix in each sequence, providing plenty of fodder for an active imagination. For myself, my brain especially likes assigning cartoon expressions to well-spaced drops in the video. What do you see? (Video and image credit: S. Sie)

A Mini Jupiter
Astronaut Don Pettit posted this image of a Jupiter-like water globe he created on the International Space Station. In microgravity, surface tension reigns as the water’s supreme force, pulling the mixture of water and food coloring into a perfect sphere. It will be interesting to see a video version of this experiment, so that we can tell what tools Pettit used to swirl the droplet into the eddies we see. Is the full droplet rotating (as a planet would), or are we just seeing the remains of a wire passed through the drop? We’ll have to stay tuned to Pettit’s experiments to find out. (Image credit: NASA/D. Pettit; via space.com; submitted by J. Shoer)

Predicting Droplet Sizes
Squeeze a bottle of cleaning spray, and the nozzle transforms a liquid jet into a spray of droplets. These droplets come in many sizes, and predicting them is difficult because the droplets’ size distribution depends on the details of how their parent liquid broke up. Shown above is a simplified experimental version of this, beginning with a jet of air striking a spherical water droplet on the far left. In less than 3 milliseconds, the droplet has flattened into a pancake shape. In another 4 milliseconds, the pancake has ballooned into a shape called a bag, made up of a thin, curved water sheet surrounded by a thicker rim. A mere 10 milliseconds after the jet and drop first meet, the liquid is now a spray of smaller droplets.
Researchers have found that the sizes of these final droplets depend on the balance between the airflow and the drop’s surface tension; these two factors determine how the drop breaks up, whether that’s rim first, bag first, or due to a collision between the bag and rim. (Image credit: I. Jackiw et al.; via APS Physics)

Self-Cleaning With Salt Critters
Even freshwater contains trace salts and minerals that cause scaly buildups as they evaporate. Getting rid of the scale usually requires toxic chemicals and/or lots of scrubbing, neither of which are desirable at the industrial level. At the same time, we’re extremely limited in the amount of freshwater that we have available; only about 1% of Earth’s water is liquid and fresh. If we could use salt water in more industrial processes, that would preserve freshwater for drinking and agriculture. But how do we tackle the scaly buildup?

(A) On microtextured surfaces, salt from evaporating drops can work its way into the gaps, destroying the superhydrophobicity of the surface. (B) In contrast, nanotextured surfaces give the salt nowhere to adhere, resulting in “salt critters” that grow upward and detach. Enter “salt critters.” Researchers found that when salt water evaporated from microtextured surfaces designed to shed water, salt would eventually build up in the gaps, breaking the hydrophobic effect and allowing scale to build up. In contrast, a nanotextured surface left nowhere for the salt to adhere. On these surfaces, evaporating salt water built jellyfish-like salt critters that rose from the surface and, eventually, broke off and rolled away, leaving the surface pristine. (Image credit: S. McBride; research credit: S. McBride et al.; via Physics Today)

The Shape of Rain
In our collective imagination, a raindrop is pendant shaped, wide at the bottom and pointed at the top. But, in fact, a falling raindrop experiences much more complicated shapes. Here, researchers blow a jet of air onto a still droplet, a good facsimile for a raindrop falling through the atmosphere. The jet of air first squishes the drop, then inflates it into a shape known as a bag. The thin sides of the bag stretch and eventually break, spraying tiny droplets. As the disintegration continues, the thick rim of the bag breaks up into big droplets. As the video demonstrates, viscosity and viscoelasticity can affect the break-up, too. (Image and video credit: I. Jackiw and N. Ashgriz)

Shaped Splashes
When a raindrop hits a leaf, it spreads out into a rimmed sheet that breaks up into droplets. These tiny drops can carry dust, spores, and even pathogens as they fly off. But many leaves aren’t smooth-edged; instead they have serrations or teeth. How does that affect a splash? That’s the question at the heart of today’s study.

A water drop hits a star-shaped pillar and breaks up. To simplify from a leaf’s shape, the team studied water dropping onto star-shaped pillars. As seen above and below, the pillar’s edge shaped the splash sheet, with the sheet extending further in the edge’s troughs. This asymmetry extends into the rim also, concentrating the liquid — and the subsequent spray of droplets — along lines that extend from the edge’s troughs and peaks.

A viscous water-glycerol drop hits a star-shaped pillar, spreads, and breaks into droplets. The team found that, in addition to sending drops along a preferred direction, the shaped edge made the droplets larger and faster than a smooth edge did. (Image and research credit: T. Bauer and T. Gilet)

“Starlit”
In “Starlit,” filmmaker Roman de Giuli leverages paint, ink, water, and oil to create astronomical views. Colorful droplets spin past like neon exoplanets. Shards of glitter form comets. Satellite droplets become moons about their larger sibling. (Video and image credit: R. de Giuli)





























