Droplets of acetone deposited on a bath of warm water can float along on a Leidenfrost-like vapor layer. The droplets are self-propelling, too, thanks to interactions between the acetone and water. Acetone can dissolve in water, and when acetone vapor beneath the drop gets absorbed into the water bath, it lowers the local surface tension. That drop in surface tension creates a pull in the direction of a higher surface tension; this is what is known as the Marangoni effect. Because of that flow in the direction of higher surface tension, the acetone drop accelerates away. (Image credit: S. Janssens et al., source)
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Molten Copper
In this video, the Slow Mo Guys prove that pouring molten copper in slow motion is every bit as satisfying as one would imagine. Because they pour the metal from fairly high up, they get a nice break-up from a jet into a series of droplets; that’s due to the Plateau-Rayleigh instability, in which surface tension drives the fluid to break up into drops. Upon impact, the copper splashes and splatters very nicely, forming the crown-like splash many are familiar with from famous photos like Doc Edgerton’s milk drop. The key difference between the molten copper and any other liquid’s splash comes from cooling; watch closely and you’ll see some of the copper solidifying along the edges and surface of the fluid as it cools. In this respect, watching the molten copper is more like watching lava flow than seeing water splash. (Video and image credit: The Slow Mo Guys)
Supporting Bubbles
Surface tension holds small droplets in a partial sphere known as a spherical cap. But when droplets become larger, they flatten out into puddles due to the influence of gravity. In contrast, soap bubbles remain spherical to much larger sizes. The bubble pictured above, for example, is more than 1 meter in radius and nearly 1 meter in height.
There is a maximum height for a soap bubble, though, and it’s set by the physical chemistry of the surfactants used in the soap. To support itself, the bubble requires a difference in surface tension between the top and bottom of the bubble. A higher surface tension is necessary at the top of the bubble to help prevent fluid from draining away. The difference in surface tension between the top and bottom of the bubble can never be greater than the difference in surface tension between pure water and the soap mixture – thus those values set a maximum height for a bubble. The researchers found their bubbles maxed out at a height of about 2 meters, consistent with their theoretical predictions. (Image credit: C. Cohen et al.; via freshphotons)
Creating Clouds
What you see here is the formation of clouds and rain – but it’s not quite what you’re used to seeing outside. This is an experiment using a mixture of sulfur hexafluoride and helium to create clouds in a laboratory. Everything is contained in a cell between two transparent plates. Liquid sulfur hexafluoride takes up about half of the cell, and when the lower plate is heated, that liquid begins evaporating and rising in the bright regions. When it reaches the cooled top plate, the liquid condenses into droplets inside the dimples on the plate, eventually growing large enough to fall back as rain. The dark wisps you see are areas where cold sulfur hexafluoride is sinking, much like in the water clouds we are used to. Setups like this one allow scientists to study the effects of turbulence on cloud physics and the formation of droplets. (Image credit: E. Bodenschatz et al., source)
Boston-area folks! I’ll be taking part in the Improbable Research show Saturday evening at 8 pm at the Sheraton Boston. Come hear about the Boston Molasses Flood and other bizarre research!
Self-Wrapping Drops
A liquid drop can fold itself up in a thin sheet. The animation above shows a drop of water with an ultra-thin (79nm) circular sheet of polystyrene atop it. As a needle removes water from the underside of the droplet, the shrinking droplet causes wrinkles and folds to form in the sheet. What’s going on here is a competition between the energy required to change the droplet’s shape and the energy needed to bend the sheet. Eventually, the droplet’s volume is small enough that the bending of the sheet overrules surface tension in dictating the droplet’s shape. The result is a tiny empanada-shaped droplet completely encapsulated by the sheet. (Image credit: J. Paulsen et al., source; research paper)
Popping
Popcorn’s explosive pop looks pretty cool in high-speed video, but just watching it with a regular camera doesn’t show everything that’s going on. If we take a look at it through schlieren optics, the kernel’s pop looks even more extraordinary:
The schlieren technique reveals density differences in the gases around the corn–effectively allowing us to see what is invisible to the naked eye. The popcorn kernel acts like a pressure vessel until the expansion of steam inside causes its shell to rupture. The first hints of escaping steam send droplets of oil shooting upward. The kernel may hop as steam pours out the rupture point, causing the turbulent billowing seen in the animation above. As the heat causes legs of starch to expand out of the kernel, they can push off the ground and propel the popcorn higher. As for the eponymous popping sound, that is the result of escaping water vapor, not the actual rupture or rebound of the kernel! See more of the invisible world surrounding a popping kernel in the video below. (Image credits: Warped Perception, source; Bell Labs Ireland, source; WP video via Gizmodo; BLI video submitted by Kevin)
Vibrated to Bits
Sound and vibration can be powerful tools for controlling liquids. In this animation, a water/glycerin drop violently bursts into a cloud of droplets when it is vibrated vertically 1000 times per second by a piezoelectric actuator. This vibration shakes the drop with accelerations of 150 g. Initially, the amplitude is small enough to simply create ripples around the drop’s circumference. As it increases, the drop deforms more at the edges and starts to eject droplets there. When the vibration hits a critical amplitude, the entire drop explodes into droplets. The technique is called vibration-induced droplet bursting, and its near-instantaneous ability to atomize drops makes it a candidate for applications like spray cooling microprocessors or spray coating a solid surface. (Video credit: B. Vukasinovic, source)
Dissolving
It looks like the fiery edge of a star’s corona, but this photo actually shows a dissolving droplet. The droplet, shown as the lower dark region in this shadowgraph image, is a mixture of pentanol and decanol sitting in a bath of water. Pentanol is a type of alcohol that is fully miscible with decanol and is water soluble, so that it will dissolve into the surrounding water over time. Decanol, on the other hand, is immiscible with water, so that part of the droplet won’t mix with the surrounding water.
The bright swirls along the droplet’s edge show areas with more pentanol. As the alcohol dissolves into the water, it forms a buoyant plume at the top of the droplet that rises due to pentanol’s lower density. That rising plume draws fresh water in from the sides, shown by the upper white arrows. Inside the droplet, flow moves in the opposite direction, from the top toward the outer edges. This is a result of uneven surface tension within the droplet. Scientists are interested in understanding the dynamics of these multiple component drops for applications like printing, where it’s desirable for pigments in an ink drop to be distributed evenly as the drop dries. (Image credit: E. Dietrich et al.)
Erie Waves
Photographer Dave Sandford braved the cold and turbulent waters of Lake Erie in late fall to capture some remarkable wave action. Like on the ocean, waves in the Great Lakes are largely driven by winds, but lakes don’t develop the constant set of rolling waves that oceans do. Instead their waves are more erratic and unpredictable. Sandford focused on capturing the moment when wind-driven waves coming into shore collided with waves rebounding from piers or rocks along the shore. The results are waves that, through Sandford’s lens, look like exploding mountainsides. Such energetic waves mix sediment and nutrients in the lake, and the spray of droplets can even loft aerosols and pollutants from the water into the atmosphere. (Photo credit: D. Sandford; via Flow Vis)
Liquid Fragmentation
From spilling coffee to driving through puddles, our daily lives are full of examples of liquids fragmenting into drops. A recently published study describes how this break-up occurs and predicts what the distribution of droplet sizes will be for a given fluid. Viscoelasticity is the property that governs this droplet size distribution. Viscoelasticity describes two aspects of a fluid–its viscosity, which acts like internal friction, resisting motion–and its elasticity, the fluid’s ability to return to its original shape after stretching. Most fluids have a little bit of each of these properties, which makes them somewhat sticky, both in the sense of not-flowing-easily and in the sense of sticking-to-itself. These same properties cause viscoelastic fluids to wind up with a broader droplet size distribution, ultimately creating both more small droplets and more large droplets than a Newtonian liquid like water. (Video credit: MIT News; research credit: B. Keshavarz et al.; submitted by mrvmt)