FYFD

Tag: surface tension

  • Transporting Droplets

    Transporting Droplets

    Transporting droplets easily and reliably is important in many microfluidic applications. While this can be done using electric fields, those fields can impact biological characteristics researchers are trying to measure. As an alternative, a group of researchers have developed the concept of “mechanowetting,” a technique that uses surface tension forces to hold droplets on a traveling wave.

    Now visually, it’s a bit tough to see what’s going on here. In the animations, it looks like the droplets are just sticking to a moving surface, but that’s an illusion. The surface the droplet is sitting on is fixed and unmoving. It’s a thin silicone film that covers a ridged conveyor belt. The belt underneath can (and does) move. This creates a traveling wave. Instead of that wave simply passing beneath the droplet, it triggers an internal flow and restoring force that helps the drop follow the wave. The effect is strong enough that small droplets are even able to climb up vertical walls or stick upside-down. (Image, research, and submission credit: E. de Jong et al.)

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    Ink Explosion

    Sometimes beautiful flows come from simple combinations. Here the artists of Chemical Bouillon combine ink and hydrocarbons to create lovely explosions of color. Eschewing quick cuts between views, they allow us to linger and explore the flow ourselves as it changes. Differences in surface tension drive streaming flows along the surface, but there seem to be some chemical reactions contributing as well. Watch along the edges and you may even see convection pulling ink down and back. The whole video is only 2 minutes long and worth a full watch. (Image and video credit: Chemical Bouillon)

  • Polygonal Droplets

    Polygonal Droplets

    Spheres are a special shape; they provide the smallest possible surface area necessary to contain a given volume. And since surface tension tries to minimize surface energy by reducing the surface area, drops and soap bubbles are, generally, spherical. There’s subtlety here, though: namely, what if reducing the surface area doesn’t minimize the surface energy?

    That’s the issue at the heart of this study. It looks at microscale oil droplets, like the ones above, that are floating in water and stabilized by surfactants. We’d expect droplets like these to be round, and above a critical temperature, they are. But as the temperature drops, the surfactant molecules along the droplet’s interface crystallize. The drop itself is still liquid, but interface is not.

    This changes the rules of the game. There’s no way for the surfactant molecules to form a sphere when solidified; they simply can’t fit together that way. So instead defects form along the interface and the drop becomes faceted. As the temperature drops further, the energy relationship between the water, oil, and surfactants continues shifting, causing the droplet to change shape – even to increase its surface area – all to minimize the overall energy. The effect is reversible, too. Raise the temperature back up above the critical point, and the interface “thaws” so that the drop becomes round again. (Image and research credit: S. Guttman et al.; via Forbes; submitted by Kam-Yung Soh)

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    Engineering Droplets

    A jet of falling liquid doesn’t remain a uniform cylinder; instead, it breaks into droplets. In this video, Bill Hammack explores why this is and what engineers have learned to do to control the size of the droplets formed.

    The technical name for this phenomenon is the Plateau-Rayleigh instability. It begins (like many instabilities) with a tiny perturbation, a wobble in the falling jet. This begins a game of tug of war. One of the competitors, surface tension, is trying to minimize the surface area of the liquid, which means breaking it into spherical droplets. But doing so requires forcing some of the the liquid to flow upward, against both gravity and the liquid’s inertia. The battle takes some time, but eventually surface tension wins and the jet breaks up.

    That’s not necessary a bad thing. It’s actually key to many engineering processes, like ink-jet printing and rocket combustion, as Bill explains in the full video. (Video and image credit: B. Hammack; submitted by @eclecticca)

  • Capillary Action and Sand Castles

    Capillary Action and Sand Castles

    Capillary action – or capillarity – is the ability of liquids to flow through narrow constrictions. It results from intermolecular forces between fluids and solids. It’s a combination of surface tension – which creates cohesion within the liquid – and adhesion, which allows the liquid and solid to hold to one another. Together, these forces propel the liquid to flow through narrow gaps.

    In the video below, a saturated mixture of sand and water is poured into a mold on a bed of dry sand. When left to settle, much of the water flows from the mold into the dry sand bed through capillary action. When the mold is removed (top), the sand holds its shape, something it can’t do without a porous bed to soak in the excess liquid. (Image and video credit: amàco et al.)

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    Drinking Coffee in Space

    You probably don’t give much thought to the forces involved in drinking here on Earth. That’s because gravity’s effects dominate over everything else. Our cups are designed to hold a liquid until we use gravity to pour it into our mouths. But that technique doesn’t work in microgravity. There other forces govern how liquids flow: specifically surface tension and capillary action.

    Both of these forces are the result of intermolecular attractions. In the case of surface tension, it’s the attraction that the molecules of a liquid feel for one another that keeps them in a cohesive bunch. Capillary action is similar, but it’s an attraction between the liquid molecules and those of the solid they’re wetting. When you combine them both, you get the ability for liquids to climb up a narrow gap and pull more liquid up behind them. That’s the key science behind every version of the “space cup” developed by astronaut Don Pettit and his collaborators. 

    To hear more about the development and engineering of the cup (and exactly why it makes drinking coffee so much more enjoyable in space than it would be otherwise) check out the full video. And, in case you’re wondering, there’s a special microgravity champagne flute, too! (Image and video credit: It’s Okay to Be Smart)

  • The Bouncing Drop

    The Bouncing Drop

    For a droplet to bounce, we expect it to hit a wall or a sharp interface of some kind. But in a new study, researchers demonstrate a droplet that bounces with neither. Shown above is an oil droplet sinking through a stratified mixture of ethanol (toward the top) and water (toward the bottom). Because the oil is heavier than ethanol, it initially sinks, dragging some of the ethanol with it as it falls. Over time, some of that ethanol rises again, forming what’s known as a buoyant jet.

    Simultaneously, the gradient of ethanol to water between the top and bottom of the drop creates an imbalance in surface tension. The ethanol near the top of the drop has a lower surface tension than the water at the bottom. This creates a downward Marangoni flow along the drop interface.

    The bounce itself happens quickly after a long, slow sinking period. As the drop’s sinking slows, the buoyant jet weakens until it disappears completely. At the same time, the downward Marangoni flow pulls fresh ethanol-rich fluid toward the top of the drop. That increases the surface tension difference and strengthens the Marangoni flow, creating a positive feedback loop. In less than a second, the Marangoni flow increases by two orders of magnitude, pulling so hard that the drop shoots upward.

    That resets the cycle by weakening the Marangoni flow and strengthening the buoyant jet. The droplet can continue bouncing for about 30 minutes until the concentration gradient is so well-mixed that the cycle can’t continue. (Image and research credit: Y. Li et al.; via APS Physics; submitted by Kam-Yung Soh)

  • Coalescence at the Smallest Scales

    Coalescence at the Smallest Scales

    The coalescence of two water droplets happens so quickly, it’s essentially impossible to see, even with high-speed cameras. For this reason, researchers have turned to simulating molecular dynamics – essentially building computer programs that model the actions of all the molecules contained in the water droplets. Viewed this way, the very first contact between drops comes from thermal fluctuations – the random jumping of molecules across the separating gap. Once the bridge starts to form, it continues to grow, driven by thermal forces and opposed by surface tension. Eventually, this thermal regime gives way to the more familiar hydrodynamic one, where the bridge is large enough for flow to drive its growth. (Image credits: experiment – S. Nagel et al.; simulation – S. Perumanath et al.; research credit: S. Perumanath et al.; submitted by Rohit P.)

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    Agnes Pockels: Surface Science Pioneer

    Today’s FYFD video tells a story I’ve wanted to share for a couple of years now. It’s about the life and work of Agnes Pockels, a woman born in the mid-nineteenth century who, despite a lack of formal scientific training, made major contributions to the understanding of surface tension and to the experimental apparatuses and methodologies used in surface chemistry in general. She accomplished all of this not in a scientific lab, but from her kitchen.

    Pockels’ story is one of curiosity, determination, and meticulous scientific inquiry. Chances are that you’ve never heard of her, but you really should. Check out the full video below to learn more! (Image and video credit: N. Sharp)

  • Magma Mixing

    Magma Mixing

    Magmas typically consist of a mixture of molten liquid, bubbles, and solid crystals. As they mix, those crystals can sink from one viscous layer into another. To investigate this sort of process, researchers studied solid particles sinking across an interface between two viscous liquids. This is what we see above. One fluid is clear; the other is dyed red, and gravity points toward the left so the particles fall from right to left.

    What happens when the particle reaches the interface between fluids depends on three main factors: the gravitational force acting on the particle, the surface tension at the interface, and the ratio of the viscosities of the two fluids. The researchers observed two main outcomes. In one (top), the particle slows at the interface and breaks through slowly, its surface wetted by the second fluid so that it drags little to none of the previous fluid with it. The researchers named this the film drainage mode. It tends to occur when the viscosity ratio between fluids is large.

    The second method, shown in the bottom image, is the tailing mode. As the particle approaches, the interface deforms. A thick layer of the first fluid coats the particle even as it pass through, forming a tail that destabilizes behind the falling particle. This mode occurs when the viscosity ratio is small or the gravitational force is large compared to the surface tension. (Image and research credit: P. Jarvis et al.)