Watch closely as a droplet freezes on a cold surface, and you’ll observe something surprising. First, a freeze front will appear, traveling upward from the substrate. It curves slightly near the edges, leaving a liquid cap atop the frozen drop. But, as we’ve all discovered, water expands as it freezes. We can watch the drop freezing and see that the water isn’t expanding radially. Instead, the water expands vertically, forming a sharp tip or cusp just as the drop freezes completely. Remarkably, the geometry of the final tip doesn’t depend on the temperature of the substrate or on the wetting contact angle. (Video credit: L. Posada)
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From Dripping to Beading
When water drips, it quickly breaks up into a string of smaller droplets due to a surface-tension-driven instability called the Plateau-Rayleigh instability. But adding just a tiny bit of polymer to the fluid changes the behavior entirely. Instead of breaking into droplets, a narrow filament dotted with tiny satellite droplets forms between the larger drops. This is known as the beads-on-a-string instability. The viscoelasticity the polymers add is one key to seeing this behavior. Polymers consist of large molecule chains that, when stretched, act a little like rubber bands–they pull back against the stretch, providing an elastic effect. Without this elasticity, the tiny filament connecting the drops would break up immediately. (Image credit: M. Berman, source; research credit: P. Bhat et al.)
Carbonation in Space
Astronauts don’t typically drink soda or other carbonated beverages while in space. The reason is probably apparent if you watch this new video of an effervescent tablet in water on the space station (or, you could watch the older classic one from Don Pettit). Unlike on Earth, where the carbon dioxide bubbles are buoyant and rise to the surface, the bubbles in a fluid in microgravity are randomly distributed. Those few bubbles that happen to be located along the edge of the water sphere will sometimes burst, creating the halo of tiny droplets you see in the video. In the case of sodas, though, the bubbles’ behavior creates a foamy mess, and, after ingestion, the bubbles are stuck travelling through the astronaut’s digestive system instead of getting burped out. Sounds rather unpleasant to me. (Video credit: NASA; submitted by entropy-perturbation and buckitdrop)
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LAST CALL: Help us do some science! I’ve teamed up with researcher Paige Brown Jarreau to create a survey of FYFD readers. By participating, you’ll be helping me improve FYFD and contributing to novel academic research on the readers of science blogs. It should only take 10-15 minutes to complete. You can find the survey here.
Raindrops in Puddles
Watching rain drops hit a puddle or lake is remarkably fascinating. Each drop creates a little cavity in the water surface when it impacts. Large, energetic drops will create a crown-shaped splash, like the ones in the upper animation. When the cavity below the surface collapses, the water rebounds into a pillar known as a Worthington jet. Look carefully and you’ll see some of those jets are energetic enough to produce a little satellite droplet that falls back and coalesces. Altogether it’s a beautifully complex process to watch happen over and over again. (Image credit: K. Weiner, source)
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Help us do some science! I’ve teamed up with researcher Paige Brown Jarreau to create a survey of FYFD readers. By participating, you’ll be helping me improve FYFD and contributing to novel academic research on the readers of science blogs. It should only take 10-15 minutes to complete. You can find the survey here.
Breaking Jets Into Drops
A falling stream of water will break into droplets due to the Plateau-Rayleigh instability. Small disturbances can create a wavy perturbation in the falling jet. Under the right conditions, the pressure caused by surface tension will be larger in the narrower regions and smaller in the wider ones. This imbalance will drive flow toward the wider regions and away from the narrower ones, thereby increasing the waviness in the jet. Eventually, the wavy jet breaks into droplets, which enclose the same volume of water with less surface area than the perturbed jet did. The instability is named for Joseph Plateau and Lord Rayleigh, who studied it in the late 19th century and showed that a falling jet of a non-viscous fluid would break into droplets if the wavelength of its disturbance was larger than the jet’s circumference. (Image credit: N. Morberg)
Sea Foam
Photographer Lloyd Meudell captures surrealistic images of breaking sea foam.
Interestingly, the sea foam is essentially a three-phase fluid made up of air, water, and sand. Yet despite the surrealism of its forms, the foam bears strong resemblance to other flows. The shapes the foam forms are reminiscent of vibrated non-Newtonian fluids like paint or oobleck. Momentum deforms the foam into sheets and ligaments smoothed and held together by surface tension until droplets snap free. You can find more of Meudell’s work at his site. (Image credits: L. Meudell; via freakingmindblowing; submitted by molecular-freedom)
Reader Question: When Mercury Meets Lava
Reader lucondri asks:
What happens when mercury touches lava?
That’s an interesting thought experiment, but hopefully no one tries it any time soon given mercury’s toxicity. So, what might happen? Mercury has a boiling point just under 630 Kelvin, and, although the temperature of molten lava varies, it’s between 970 and 1470 Kelvin when it first erupts. So mercury would definitely vaporize (i.e. boil) on contact with lava. (Again, this is very bad for anyone nearby.) If you’re curious what boiling liquid mercury looks like, wonder no further.
Molten lava is much, much hotter than the boiling point of mercury, though, so there’s a possibility that the mercury won’t boil away instantly. This is because of the Leidenfrost effect, where a thin layer of vapor forms between a liquid and an extremely hot surface. The vapor has such low friction that the liquid can essentially skate across a surface, and it doesn’t boil away instantly because the vapor insulates it from the extreme heat. After some digging, I found a paper that placed the Leidenfrost temperature of mercury between about 850 and 950 Kelvin, meaning that fresh lava is probably hot enough to generate mercury Leidenfrost drops.
So pouring a lot of mercury on lava will probably result in some boiling, but there’s also a good chance that it will form a bunch of skittering mercury droplets that will stick around awhile before they evaporate into toxic mercury gas. That said, it’s a lot easier and safer to watch awesome Leidenfrost drop videos with other liquids. (Collage credit: N.Sharp; images sources: Z. T. Jackson, and A.Biance)
Asteroid Impact
I often receive questions about how fluids react to extremely hard and fast impacts. Some people wonder if there’s a regime where a fluid like water will react like a solid. In reality, nature works the opposite way. Striking a solid hard enough and fast enough makes it behave like a fluid. The video above shows a simulated impact of a 500-km asteroid in the Pacific Ocean. (Be sure to watch with captions on.) The impact rips 10 km off the crust of the Earth and sends a hypersonic shock wave of destruction around the entire Earth. There’s a strong resemblance in the asteroid impact to droplet impacts and splashes. Much of this has to do with the energy of impact. The asteroid’s kinetic (and, indeed, potential) energy prior to impact is enormous, and conservation of energy means that energy has to go somewhere. It’s that energy that vaporizes the oceans and fluidizes part of the Earth’s surface. That kinetic energy rips the orderly structure of solids apart and turns it effectively into a granular fluid. (Video credit: Discovery Channel; via J. Hertzberg)
Laser-Made Superhydrophobics
Superhydrophobic surfaces are so repellent to water that liquids often cannot wet them. Today these surfaces are usually created with chemical coatings or deliberate manufacturing to create micro- and nanoscale structures that trap air between the drop and the surface in order to prevent adhesion. Researchers recently announced they’ve made metals superhydrophobic with laser treatments. The process is still time-consuming, but they hope it can be scaled up for wider applications. Because drops bounce so readily off the treated surfaces, it takes very little water to clean them, which may be especially useful for sanitation purposes in the developing world. Superhydrophobic materials are also good for preventing icing on aircraft wings. To learn more about the research, check out the University of Rochester’s video explanations. (Image credit: C. Guo et al., source videos 1,2; submitted by entropy-perturbation and buckitdrop)
How Rain Gets Its Smell
Light rain after a dry spell often produces a distinctive earthy scent called petrichor that is associated with plant oils and bacteria products. How these chemicals get into the air has been unclear, but new research suggests that the mechanism may come from the rain itself. When water falls on a porous surface like soil, tiny air bubbles get trapped beneath the drop. These bubbles rise rapidly due to buoyancy and, upon reaching the surface, burst and release tiny droplets known as aerosols. Depending on the surface properties and the drop’s impact speed, a single drop can produce a cloud of aerosol droplets. The research team is now investigating how readily bacteria or pathogens in the soil can spread through this mechanism. Other human-focused research has already shown that these tiny aerosol droplets can persist in the air for remarkably long periods and may help spread diseases. (Video credit: Massachusetts Institute of Technology; research credit: Y. Joung and C. Buie; submitted by Daniel B and entropy-perturbation)