FYFD

Tag: chemistry

  • Spreading By Island

    Spreading By Island

    How does a droplet sinking through an immiscible liquid settle onto a surface? Conventional wisdom suggests that the settling drop will slowly squeeze the ambient fluid film out of the way, form a liquid bridge to the solid beneath, and spread onto the surface. But for some droplets, that’s not how it goes.

    While watching a glycerol droplet settle through silicone oil, researchers discovered a new mechanism for wetting. Initially, the silicone oil drained from beneath the drop, as expected. But then the thinning of the film stalled. Tiny bright spots (above) appeared beneath the light and dark interference fringes of the parent drop. These are spots of glycerol, formed when material from the main drop dissolved into the oil and then nucleated onto the solid surface below. Over time, the island-like spots of glycerol grew. Eventually one grew large enough to coalesce with its parent drop (below), causing the glycerol to quickly spread over the solid surface!

    Islands nucleate and grow beneath a droplet until they're able to coalesce with the parent droplet above.
    Islands of liquid (darker rings) grow beneath a parent drop (brighter rings) until reaching a size where they coalesce, causing the interference fringes to disappear.

    The key to this phenomenon seems to be that immiscibility isn’t perfect. Even trace amounts of solubility between the drop and surrounding fluid are enough to allow these islands to form. And once formed, the islands will grow as long as the drop fluid and the solid surface are chemically attractive. (Image, research, and submission credit: S. Borkar and A. Ramachandran; see also Nature Behind the Paper)

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    Ink-Based Propulsion

    In this video, Steve Mould explores an interesting phenomenon: propulsion via ballpoint pen ink. Placing ink on one side of a leaf or piece of paper turns it into a boat with a dramatic dye-filled wake. It’s not 100% clear what’s happening here, though I agree with Steve that there are likely several effects contributing.

    Firstly, there’s the Marangoni effect, the flow that happens from an area of low surface tension to high surface tension. This is what propels a soap boat as well as many water-walking insects. I think this is a big one here, and not just because the ink has surfactants. As any component of the ballpoint ink spreads, its varying concentration is going to trigger this effect.

    Secondly, there’s a rocket effect. Rockets operate on a fairly simple principle: throw mass out the back in order to go forward. These dye boats are also doing this to some extent.

    And finally there’s some chemistry going on. Some kind of reaction seems to be taking place between one or more of the ink components and the water in order to create the semi-solid layer of dye. Presumably this is why the dye doesn’t simply dissolve as it does in some of Steve’s other experiments.

    I figure some of my readers who are better versed in interfacial dynamics, rheology, and surface chemistry than I am will have some more insights. What do you think is going on here? (Video and image credit: S. Mould)

  • Devising Greener Chemistry

    Devising Greener Chemistry

    Not all microfluidic devices use tiny channels to pump and mix fluids. Some, like the Vortex Fluidic Device (VFD), conduct their microfluidic mixing in thin films of fluid. The VFD is essentially a tube spinning at several thousand RPM that can be tilted to various angles. Coriolis forces, shear, and Faraday instabilities in the thin fluid film create a complex microfluidic flow field that’s excellent for mixing, crystallization, and processing of injected chemicals. One rather notorious application of this device was unboiling an egg, a feat for which the researchers won an Ig Nobel Prize. But other, more practical applications abound, including a waste-free method for coating particles. (Image and research credit: T. Alharbi et al.; video credit: Flinders University; via Cosmos; submitted by Marc A.)

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    “Columbia”

    “Columbia” is a music video illustrated with fluid dynamics, chemistry, and biology by the Beauty of Science team. It’s got everything from precipitation to crystallization, from infrared imagery of wakes to timelapses of growing molds. How many phenomena can you identify? (Video and image credit: Beauty of Science)

  • A Macro View of Weathering

    A Macro View of Weathering

    Water constantly weathers sedimentary rock, both physically — through abrasion — and chemically — through dissolution and recrystallization. Now researchers have gotten their first view of this weathering at the Ångstrom level by observing porous rocks with environmental transmission electron microscopy as they interact with both water vapor and liquid water.

    As expected, the experiments with liquid water showed that water dissolved the rocks and substantially changed the geometry of the rock’s pores. But the experiments also showed significant weathering from water vapor alone. The researchers found that water vapor formed a film on the surface of the rock’s pores in a process known as adsorption. This film substantially decreased the size of each pore and created strain in the rock. Once the water vapor was removed, the rock’s pores were notably altered, supporting the idea that this adsorption was, itself, a form of weathering. (Image credit: M. Kosloski; research credit: E. Barsotti et al.; via AGU EOS; submitted by Kam-Yung Soh)

  • Acidic Sea Spray

    Acidic Sea Spray

    As waves crash and break, they generate a spray of droplets — known as aerosols — that make their way into the atmosphere. Researchers investigated the chemistry of these aerosol droplets by generating spray in a wave tank filled with ocean water. They found that aerosol droplets are far more acidic than the ocean they come from, and the smaller the droplet, the more acidic it is. This acidification happens in a matter of minutes, as acidic gases interact with the spray. Their findings will be critical for accurately modeling the climate connections between our oceans and atmosphere. (Image credit: Elle; research credit: K. Angle et al.; via OceanBites; submitted by Kam-Yung Soh)

  • “Catalysis”

    “Catalysis”

    Catalysts speed up chemical reactions without being consumed themselves. In “Catalysis” the Beauty of Science team shows 5 different examples of catalytic reactions, from acetone oxidation to yeast fermentation. The film is full of bubbles, sparks, and wave-like pulses of chemical reaction. As always, it’s a lovely glimpse of processes we’re not used to watching so closely. (Image and video credit: Beauty of Science)

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    Precipitation

    Chemistry and fluid dynamics often go hand-in-hand. Here chemical reactions produce visible precipitates as one chemical drops into the other. The shapes that form are distinctly fluid dynamical, with vortex rings, plumes, and instabilities all appearing.

    In many applications, chemical reactions and fluid dynamics are tied inextricably to one another because the rate of chemical reaction depends on local concentrations driven by fluid dynamics, and the fluid motion is itself influenced by those concentration gradients. This is why reacting flows, like those found in combustion, are among the hardest topics in fluids. (Image and video credit: Beauty of Science)

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    Hot Ice, Buoyancy Tricks, and More DIY Fun

    Here’s a smorgasbord of DIY experiments from Dianna at Physics Girl. Some are fluidsy, some aren’t, but all of them give you a chance to stretch your science muscles at home. Personally, I think she saved the best for last with her laser-acoustics demo! (Video credit: Physics Girl)

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    Fluorescent Dancing Droplets

    These fluorescent droplets of glowstick liquid jiggle and dance in a solution of sodium hydroxide. Some droplets jitter. Some rotate. And some undergo one coalescence after another. It’s always fun to see how fluid dynamics and chemistry combine! (Image and video credit: Beauty of Science)