FYFD

Tag: chemistry

  • Weathering Spilled Oil

    Weathering Spilled Oil

    As long as we continue to extract and transport oil, marine oil spills will continue to be a problem. Recent work shows that spilled oil weathers differently depending on both sunlight and water temperature. When exposed to sunlight, crude oil undergoes chemical reactions that can change its makeup. Researchers studied the mechanical properties of crude oil samples kept at different temperatures in both sunlight and the dark.

    They discovered that sunlight-exposed crude oil kept at a high temperature had twice the viscosity of a sample kept in the dark at the same temperature. In contrast, the high-temperature sunlit sample’s viscosity was 8 times lower than a sunlit sample kept at a lower temperature. That’s quite a large difference, and it implies that tropical oil spills may behave quite differently than Arctic ones. Cold-water spills will entrain and dissolve less than warm-water ones, so there may be more surface oil to collect at high-latitude spills. The differences in viscosity may also necessitate different spill mitigation techniques. (Image credit: NOAA; research credit: D. Freeman et al.; via APS Physics)

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    “aBiogenesis”

    Many theories posit the physical and chemical origins of life. In the short film “aBiogenesis”, CGI artist Markos Kay imagines one such theory — the lipid world theory — in which cellular life began as a soup contained within immiscible fatty membranes. Chemicals trapped within these vesicles interacted and ultimately formed the building blocks of life as we know it, including RNA. Kay’s interpretation is a beautiful exploration of this intersection of physics, chemistry, and biology. (Image and video credit: M. Kay; via Colossal)

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    Chemical Flowers

    These “flowers” blossom as two injected chemicals react in the narrow space between two transparent plates. The chemical reaction produces a darker ring that develops a streaky outer edge due to competition between convection and chemical diffusion.

    To show how gravity affects the instability, the researchers repeated the experiment on a parabolic flight. In microgravity conditions, no instability formed. That’s exactly what we’d expect if convection (i.e. flow due to density differences) is a major cause. No gravity = no convection. In contrast, under hypergravity conditions, the instability was initially spotty before developing streaks. (Image and video credit: Y. Stergiou et al.)

  • Acidic Aerosols

    Acidic Aerosols

    As ocean waves crash, they generate aerosols — tiny liquid and solid particulates — that interact with the atmosphere. Curious about the chemistry of these tiny drops, researchers set out to measure their acidity. That’s easier said than done. Over time, aerosol droplets acidify as they interact with acidic gases in the atmosphere and capturing fresh aerosols in the field is next to impossible.

    To tackle these challenges, researchers instead moved the aerosols to the laboratory, filling a wave channel with seawater and agitating it to generate aerosols they could then measure. They found that the smallest aerosols become a million times more acidic than the bulk ocean in only two minutes! Find out more about their experiment and its implications over at Physics Today. (Image credit: E. Jepsen; research credit: K. Angle et al.)

  • Dispelling Ice

    Dispelling Ice

    In winter weather, delays pile up at airports when planes need de-icing. Our current process involves spraying thousands of gallons of chemicals on planes, but these chemicals are easily removed by shear stress and dissolution, meaning that by the time a plane takes off, there is little to no de-icing agent remaining on the plane. Instead, those chemicals become run-off.

    Researchers looking to change that have developed a family of anti-icing coatings — including creams, sprays, and gels — that are easy to use and apply, non-toxic, and much longer lasting than conventional methods. Ice slides easily off their gel coatings, which remain optically transparent even under freezing conditions — and ice can take 25 times longer to form on the gels compared to current anti-icing tech.

    The team envisions using their coatings on much more than airplanes. Imagine traffic lights that can’t be obscured by ice or snow, a windshield on your car that never freezes over, or even an anti-icing spray that could protect crops from a sudden freeze! (Image, video, research, and submission credit: R. Chatterjee et al.; see also)

  • Mixing the Immiscible

    Mixing the Immiscible

    Immiscible liquids — like oil and water — do not combine easily. Typically, with enough effort, you can create an emulsion — a mixture formed from droplets of one liquid suspended in the other — like the one above. But a team of researchers have taken mixing immiscible liquids to a new level using their Vortex Fluid Device (VFD).

    Longtime readers may remember the group from their Ig-Nobel-winning demonstration of unboiling an egg, but this time the team is used the VFD to mix and de-mix immiscible liquids. As shown in the video below, the VFD is essentially a fast-spinning tube tilted at a 45-degree angle. As it spins, the liquids inside are forced into thin films with very high shear rates — high enough that immiscible liquids like water and toluene are forced together without forming an emulsion. Essentially, the mechanical forces mixing the liquids are strong enough to overcome the chemistry that typically keeps them apart.

    Impressively, the device manages this without using harsh surfactants or catalysts that other methods rely on. As a result, the technique offers a greener method for mixing chemicals for pharmaceuticals, cosmetics, food processing, and more. (Image credit: pisauikan; research credit: M. Jellicoe et al.; video credit: Flinders University; submitted by Marc A.)

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    “Belletrix”

    Icy crystals burst forth against a dark background in Thomas Blanchard’s short film “Belletrix.” The process is one of chemical crystallization. Blanchard supersaturates a chemical in a dish of hot water, then cools the fluid, which then spontaneously crystallizes when disturbed. Depending on the solution’s temperature, the crystals vary from feather-like to radial stars, each reflecting, expanding, and overlapping to cover the full surface. (Image and video credit: T. Blanchard)

  • Liquid Bridges

    Liquid Bridges

    In 1893, Baron Armstrong demonstrated a peculiar phenomenon — a liquid bridge of water suspended between two beakers with a strong electric charge between them (Image 1). More than a century later, the details of the mechanism remain challenging to pin down thanks to the setup’s combination of electohydrodynamics, heat transfer (Image 2), evaporation, and chemistry (the electrodes can split water).

    Researchers have pinned down a few details, though, like that the break-up of the liquid bridge (Image 3) depends on its effective length and that the effective length grows as applied voltage increases. Researchers also found that inducing an external flow can extend the bridge’s lifetime, though it does not affect the length at which it breaks up. Interestingly, the phenomenon is not limited to water (and its odd chemistry); ethanol and glycerol have been used for liquid bridges, too! (Image and research credit: X. Pan et al.)

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    “Halo”

    Fluids create mesmerizing practical effects in this new experimental film from the Julia Set Lab. I love how the visuals mess with your sense of scale. Some of the sequences look like they could be a solar firestorm or disintegrating sea ice, though in reality the camera’s field of view is probably smaller than your palm. The filmmakers provide no information on the fluids they use, but I spy some hints of partially miscible ingredients, some chemical reactions, and plenty of Marangoni action. (Video and submission credit: S. Bocci/Julia Set Lab)

  • Changing with the Flow

    Changing with the Flow

    Chemically-reacting flows are some of the toughest problems to unravel. In this new study, researchers found that the very act of flowing through narrow channels can change the speed of chemical reactions. In particular, they found that protein molecules carried through a capillary tube (comparable in size to human capillaries) changed their local shape as a result of the shear forces they experienced. Those changes actually sped up the proteins’ chemical reactions compared to the reaction speed for the chemicals in bulk.

    That finding suggests two important takeaways: 1) chemicals may be absorbed in the human bloodstream differently in capillaries than in other parts of the cardiovascular system, and 2) mimicking these tiny capillaries in microfluidic devices could be useful in speeding up certain biochemical reactions. (Image credit: top – KazuN, visual abstract – T. Hakala et al.; research credit: T. Hakala et al.; via Science; submitted by Kam-Yung Soh)

    Graphical abstract showing that shear forces in small channels can cause local changes to protein structure that affect the rate of chemical reactions.