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Tag: Leidenfrost effect

  • The Vortex Beneath a Drop

    The Vortex Beneath a Drop

    While we’re most used to seeing levitating Leidenfrost droplets on a solid surface, such drops can also form above a liquid bath. In fact, the smoothness of the bath’s surface, combined with mechanisms discussed in a new study, means that drops will levitate at a cooler temperature over a liquid than they will over a solid surface.

    Researchers found that a donut-shaped vortex forms in the bath beneath a levitating droplet, but the direction of the vortex’s circulation is not always the same. For some liquids, the flow moves radially outward from beneath the drop. In this case, researchers found that the dominant force was shear stress caused by the vapor escaping from under the droplet.

    With other droplet liquids, the flow direction instead moved inward, forming a sinking plume beneath the center of the drop. In this situation, researchers found that evaporative cooling dominated. As the liquid beneath the droplet cooled, it became denser and sank. At the same time, the lower temperature changed the bath’s local surface tension, creating the inward surface flow through the Marangoni effect. (Image credit: F. Cavagnon; research credit: B. Sobac et al.)

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    Mixing Leidenfrost Drops

    When placed on a very hot, patterned surface, droplets will self-propel on a layer of their own vapor. Here, researchers use this to drive droplets to coalesce so that they can observe how well they mix. After their head-on collision, the merged droplets have two major forces fighting in them: surface tension, which tries to minimize the overall surface area; and gravity, which tries to flatten the large droplet. Together, these forces drive the large oscillations we see in the merged drop, and those oscillations help mix the liquid from the two original drops together. (Image, video, and research credit: Y. Chiu and C. Sun)

  • Leidenfrost Stars

    Leidenfrost Stars

    Atop a very hot surface, liquids can instantly vaporize, leaving a drop levitating on a layer of its own vapor. These Leidenfrost droplets demonstrate all kinds of interesting behaviors, including self-propulsion, explosion, and star-shaped oscillations, like those above. The oscillation is driven by feedback between the drop and its vapor layer. 

    Interestingly, the drops are capable of sustaining more than one mode of oscillation at once, as seen above. The obvious mode (m=5) corresponds to the 5 star-like points pushing out on the drop. But notice that the drop is also stretching into an oval shape that moves up and down, back and forth. This is the second mode (m=2) present. It moves slower than the m=5 mode, completing a cycle only once for every four cycles the other has. (Image and research credit: J. Bergen et al.)

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    Drops That Dig

    On extremely hot surfaces, droplets will skitter on a layer of their own vapor, thanks to the Leidenfrost effect. This keeps the liquid insulated from contact with the hot surface. But what if the surface isn’t solid?

    That situation is what we see above. Instead of soaking into a granular material like a room temperature droplet (left), a drop falling onto a very hot bed of grains digs a hole! As with a typical drop on a super hot surface, the heat vaporizes part of the droplet. As the vapor escapes, it carries sand with it, allowing the boiling drop to burrow its way into the material. As the temperature difference between the sand and droplet changes, the digging slows. Eventually, the drop comes to a rest and boils away. (Video and image credit: J. Zou et al.)

  • The Leidenfrost Crack

    The Leidenfrost Crack

    In 1756, Leidenfrost reported on the peculiar behaviors of droplets on surface much hotter than the liquid’s boiling point. Such droplets were highly mobile, surfing on a thin layer of their own vapor and were prone to loud cracking noises.

    More recently, scientists have observed that drops with an initially small radius eventually rocket off the hot surface whereas larger drops end their lives in an explosion (above) – the source of Leidenfrost’s crack. Now researchers have explained why drops of different sizes have such different fates. The key is their level of contamination.

    To reach the take-off radius, the drop has to evaporate a significant portion of its volume. For an initially-large drop, that’s tough because any solid contaminants in the drop will build up along the surface of the drop as it shrinks. Eventually, they restrict the liquid from evaporating, which thins the vapor layer the drop sits on. It sinks until a part of it touches the surface. The sudden influx of heat from the surface explosively destroys whatever remains of the drop. (Image and research credit: S. Lyu et al.; via Brown University; submitted by gdurey)

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    Fizzy Droplets

    Leidenfrost drops surf on a layer of their own vapor, created by the high temperature of a nearby surface relative to their boiling point. These Leidenfrost drops can self-propel and skitter and skate across a surface, but they’re not the only droplets that do this. In this video, researchers show how a drop of carbonated water on a superhydrophobic (water-repelling) surface also avoids contact. As long as the drop has carbon dioxide to expel, it will maintain a gap relative to the surface and can even surf over a ratcheted surface the way that their Leidenfrost cousins do. (Image and video credit: D. Panchanathan et al., source)

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    Swirling Polygons

    We don’t usually think of fluids forming corners, but they can. Here you see liquid nitrogen in a simple pot. Since the pot is much hotter than the boiling point of the nitrogen, the liquid nitrogen is floating on a layer of its own vapor. This is called the Leidenfrost effect. That nearly frictionless contact with the pot means that stirring the nitrogen conveniently spins it up into these rotating polygons, visible in high-speed footage. The faster you stir the nitrogen, the more points you get. 

    Check out the full video below for instructions on how the researchers constructed their set-up. If you try it, though, remember to have plenty of ventilation. When the nitrogen vaporizes, its volume increases dramatically, and if you’re not careful, it will displace too much oxygen and make it hard to breathe. (Image and video credit: A. Duchesne et al., source)

  • Exploding a Drop

    Exploding a Drop

    Leidenfrost drops levitate over a hot substrate on a thin layer of their own vapor, constantly replenished as the drop evaporates. For the most part, previous studies have focused on pure droplets, but a new one looks at what happens when you add surfactants – and the results are, well, explosive.

    Surfactants are a type of chemical that like to gather at the surface of a drop, and, unlike water, they’re nonvolatile – they don’t evaporate easily. So as the Leidenfrost drop evaporates and shrinks, the surface of the drop becomes more and more crowded with surfactant molecules. Eventually, they form an elastic shell around the remaining water, making evaporation more difficult.

    Inside the droplet, the temperature continues to rise, eventually reaching a point where bubbles of vapor can nucleate inside. When that happens, the bubbles expand almost instantaneously and the internal pressure spike bursts the shell, causing the entire droplet to explode. (Image and research credit: F. Moreau et al.)

  • Lava Bomb

    Lava Bomb

    What you see above is a homemade lava bomb. To systematically study what happens when groundwater meets lava, scientists melted basalt and created their own meter-scale explosion-on-demand. Inside the container, they can inject water and observe the resulting dynamics.

    Beneath the lava, the water forms what scientists call a domain. Thanks to the Leidenfrost effect, it can be protected from direct contact with the lava by a thin vapor layer that boils off it. If the water domain is large enough, buoyancy will pull it upward through the lava. Whether the water maintains a spherical shape or begins to distort and break up into smaller domains depends on the speed of its rise.

    At some point, though, either naturally or through an external trigger (like the sledgehammer you see above), the water and lava can contact, resulting in explosive vaporization of the water and an explosion. What’s visible at the surface depends on the depth at which the explosion takes place. Scientists are eager to characterize these variations, which will help them better predict the explosive danger of eruptions like Kilauea and Eyjafjallajökull. (Image and research credit: I. Sonder et al.; video credit: NYTimes; submitted by Kam-Yung Soh)

  • Wheeling Drops

    Wheeling Drops

    Leidenfrost drops – which skitter almost frictionlessly across extremely hot surfaces on a thin layer of their own vapor – are notoriously mobile. We’ve seen numerous methods of controlling their propulsion, often using specially-shaped surfaces. But it turns out that some Leidenfrost drops can self-propel even on a smooth, flat surface (top image). 

    Internally, large Leidenfrost drops have complicated, but symmetric flows that are driven by temperature and surface tension variations across the drop. But as the drop evaporates, that symmetry eventually gets broken, leaving behind a single large circulating flow. 

    Beneath the drop, that internal circulation affects the vapor layer. It causes the layer to take on an overall tilt, and the rotation, along with that slight angle in the vapor layer, causes the Leidenfrost drop to roll away like a wheel. (Image and research credit: A. Bouillant et al.; via NYTimes)