The shape of a droplet sitting on a surface depends, in part, on its surface tension properties but also on the nanoscale roughness of the surface. Small variations in the height and shape of the surface will change the area a drop contacts as well as the contact angle the edge of the drop makes with the surface. If the contact line between the drop and surface stays the same as a droplet evaporates into the surrounding gas or dissolves into the surrounding liquid, then we say the drop is pinned. A pinned drop’s contact angle will decrease as the drop’s volume decreases. This strains the ability of the nanoscale roughness to keep the drop’s edge pinned. As individual points of contact fail, the drop’s edge may jump inward to a new contact point. This set of discrete jumps between pinned states is called a stick-jump or stick-slip mode. (Image credit: E. Dietrich et al., source; see also: E. Dietrich et al. 2015)
Tag: dissolution
Icebergs and Caramel
What do icebergs and caramel have in common? Both have similar scalloped erosion patterns as they dissolve. When caramel dissolves in water, the denser caramel sinks in the buoyant water. An initially smooth surface will first form lines, then the flowing caramel and the uneven surface interact, forming chevrons, followed by larger scallops. A similar process happens with melting icebergs. The meltwater from an iceberg is less dense than the surrounding seawater, so it will rise as it melts. This causes variations in the salt concentration and temperature near the iceberg, which cause it to melt differently in different spots, ultimately leading to the same scallop shapes observed in the caramel. Check out the full-size PDF of the poster here. (Image credit: C. Cohen et al.)
