The Leidenfrost effect occurs when a liquid encounters a solid object much hotter than the liquid’s boiling point, like when water skitters on a hot griddle or someone plunges a hand in liquid nitrogen. A thin layer of vapor forms between the liquid and the solid, thereby (briefly) insulating the remaining liquid. The Leidenfrost effect can be static–like a droplet sitting on a pan–or dynamic, like the video above in which a droplet impacts the hot object. The video shows both a top and a side view of a droplet striking a plate that is over five times hotter than the liquid’s boiling point. On impact, the droplet spreads and flattens, and a spray of even tinier droplets is ejected before rebound. (Video credit: T. Tran and D. Lohse, from a review by D. Quere)
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The Archer Fish’s Arrows
The archer fish hunts by shooting a jet of water at insects in the leaves above and knocking them into the water. How the fish achieve this feat has been a matter of contention. A study of high-speed video of the archer’s shot shows that fluid dynamics are key. The fish releases a pulsed liquid jet, imparting greater velocity to the tail of the jet than the head. As a result, the tail tends to catch up to the head and increase the jet’s mass on impact while decreasing the duration of impact. Simultaneously, the jet tends to break down into droplets via the Rayleigh-Plateau instability caused by surface tension. Surface tension’s power to hold the water in droplets combined with the inertial effects of the pulsed jet create a ball of fluid that strikes the archer’s prey with more than five times the power than vertebrate muscles alone can impart. For more on archer fish, check out this video and the original research paper by A. Vailati et a. (Photo credits: Scott Linstead and BBC; submitted by Stuart R)
Liquid Lenses
Here astronaut Andre Kuipers demonstrates fluid dynamics in microgravity. A roughly spherical droplet of water acts as a lens, refracting the image of his face so that it appears upside down. The air bubble inside the droplet refracts the image back to our normal perspective again. (Photo credit: Andre Kuipers, ESA; via Bad Astronomy)
Boiling Without Bubbles
Water droplets sprinkled on a sufficiently hot frying pan will skitter and skate across the surface on a thin layer of vapor due to the Leidenfrost effect. When a solid object is much warmer than a liquid’s boiling temperature, the surface is surrounded by a vapor cloud until the solid cools to the point that the vapor can no longer be sustained. Then the vapor breaks down in an explosive boiling full of bubbles. Unless, as researchers have just published in Nature, the solid is treated with a superhydrophobic coating. The water-repellent surface prevents the bubbling, even as the sphere cools. The technique could be used to reduce drag in applications like the channels of a microfluidic device. (Video credit: I. Vakarelski et al.; see also Nature News; submitted by Bobby E)
Astro Puffs
Microgravity continues to be a fascinating playground for observing surface tension effects on the macroscale without pesky gravity getting in the way. Here astronaut Don Pettit has created a sphere of water, which he then strikes with a jet of air from a syringe. Initially, the momentum from the jet of air creates a sharp cavity in the water, which rebounds into a jet of water that ejects one or more satellite drops. Surface waves and inertial waves (inside the water sphere) reflect back and forth until the fluid comes to rest as a sphere once more. Note how similar the behavior is to the pinch-off of a water column. Both effects are dominated by surface tension, but on Earth we can only see this behavior with extremely small droplets and high-speed cameras! (Video credit: Don Pettit, Science Off the Sphere)
Science off the Sphere: Thin Films
Stuck here on Earth, it’s hard to know sometimes how greatly gravity affects the behavior of fluids. Fortunately, astronaut Don Pettit enjoys spending his free time on the International Space Station playing with physics. In his latest video, he shows some awesome examples of what is possible with a thin film of water–not a soap film like we make here on Earth–in microgravity. He demonstrates vibrational modes, droplet collision and coalescence, and some fascinating examples of Marangoni convection.
Liquid Nitrogen and the Leidenfrost Effect
One of the tried and true cooking tips my mother gave me when I was younger was to test the temperature of my griddle before making pancakes by splashing a few drops of water on it. If it was hot enough that the water skittered across the surface before evaporating, then it was ready. Aside from being a way to make great pancakes, this tip demonstrates an everyday application of the Leidenfrost effect. When the surface of the pan is significantly higher than the boiling point of the water, the part of the water drop that hits the pan is vaporized, creating a thin layer of water vapor on which the rest of the droplet rests. The vapor serves as an insulator, protecting the rest of the water drop from the heat of the pan, as well as a lubricant, allowing the drop slip and slide easily across the surface. The same effect lets the brave plunge a hand into liquid nitrogen without damage, but they have to be quick, otherwise their hand will cool to the point that the liquid nitrogen contacts it without a protective layer of nitrogen. (In that case, a nasty case of frostbite may be the least of one’s worries. We do NOT recommend trying this one at home.)
The Gobbling Drop
A little polymer goes a long way when it comes to changing a fluid’s behavior. Normally, a falling jet of fluid will develop waviness and be driven by surface tension and the Plateau-Rayleigh instability to break up into a stream of droplets. We see this at our water faucets all the time. But when traces of a polymer are dissolved in water, the behavior is much different. The viscoelasticity of the polymer chains creates a force that opposes the thinning effects caused by surface tension. So, instead of thinning to the point of breaking into droplets, a drop is able to climb back up the jet until it reaches a critical mass where it reverses direction, accelerates downward due to gravity and eventually breaks off the jet. Then the whole process begins again with a new terminal drop. (Video credit: C. Clasen et al)
Making Mixed Emulsions
Ever tried to mix oil and vinegar? Anyone who has ever dealt with salad dressings knows the difficulty of evenly distributing immiscible fluids; the key is to shake them and create an emulsion, where droplets of one fluid are distributed throughout another. In this video, researchers create a double emulsion–oil in water in oil–without touching the two fluids. First they suspend a drop of water on a wire and then coat it with oil. Below, they place a bath of silicone oil, which they vibrate. When the oil-coated droplet falls onto the bath, it bounces on the surface rather than coalescing because a thin layer of air–constantly refreshed due to the vibration of the surface–separates the droplet from the bath. When the amplitude of the vibration is large enough, the oil coating penetrates the water during the bounce, leaving behind a tiny droplet and creating the emulsion. (Video credit: D. Terwange et al; Research paper)
Fragmenting Raindrops
This numerical simulation demonstrates the fragmentation of droplets of water falling through a quiescent medium–essentially how a raindrop behaves. As the initial droplet falls, drag forces deform the droplet, contorting it until surface tension causes it to break into smaller droplets, which can themselves be broken up by the same mechanisms.