An evaporating drop of ouzo goes through several stages due to the interactions of oil, alcohol and water. If you turn the situation around by placing a drop of (blue-dyed) water in a mixture of alcohol and anise oil (top image), you get some similarly odd behavior. The drop of water shimmies and grows as alcohol dissolves into it, carrying the occasional oil droplet with it. Eventually, the droplet grows large enough and buoyant enough that part of it detaches and floats to the surface (middle image). If you increase the alcohol ratio in the surrounding fluid, you speed up this process, causing droplets to stream up to the surface (bottom image). (Image and video credit: O. Enriquez et al., source)
Category: Research

Phase-Switching to Avoid Icing
Preventing ice and frost from forming on surfaces – especially airplane wings – is a major engineering concern. The chemical de-icing cocktails currently used in aviation are a short-lived solution, and while superhydrophobic surfaces can be helpful, they tend to be easily damaged and therefore impractical. Another possible solution, shown here, are so-called phase-switching liquids – substances like cyclohexane that have freezing points higher than that of water. This means that they form a solid coating near the freezing temperature of water.
Water droplets on these coatings move in a random stick-slip walk (above) but they tend not to freeze. This is because freezing requires the droplets to release heat, which melts part of the phase-switching liquid. Now, instead of solidifying to the surface, the droplet moves on a film of the phase-switching liquid. Re-freezing that liquid is tough because it’s thermodynamically unfavorable, and the smoothness of the liquid layer makes it harder for ice to find a nucleation point. In lab tests, the phase-switching liquid surfaces resisted ice and frost more than an order of magnitude longer than conventional materials. (Image and research credit: R. Chatterjee et al.; video credit: Univ. of Illinois at Chicago; submitted by Night King)

The Color of Droplets
In nature, color comes from many sources: like the pigmentation of skin and hair, the structural iridescence of a butterfly’s wings, or the refraction of a rainbow from water droplets. Recently, scientists discovered another source of brilliant color in simple, hemispherical water droplets.
When small droplets form on a transparent surface, they form concave shapes capable of total internal reflection. This means that two light rays entering from the same angle can follow different paths inside the droplet. After reflecting several times, the light rays exit the droplet with a phase difference and how large that phase difference is determines the color. Check out the video below for some brightly colored examples of the effect. The researchers hope the technique will eventually be suitable for creating dye-free, color-changing technologies. (Image credit: F. Frankel; video credit: MIT News; research credit: A. Goodling et al.)

Forming a Waterfall
Many factors can affect a waterfall’s formation – changes in bedrock structure, tectonic shifts, and glacial motion, to name a few. But a new study suggests that some waterfalls may be self-forming. Using a lab-scale experiment, researchers created a homogeneous “bedrock” out of polyurethane foam, which they eroded with a combination of constant water flow and particulates. Even without external perturbations, the flow carved out a series of steps.
As a pool deepened, particles built up inside, armoring the bed against further erosion. But further downstream, the chute continued to erode, steepening the area between them until a waterfall formed. On the timescale of the experiment, the waterfalls lasted only 20 minutes or so, but that’s equivalent to up to 10,000 years in geological time. (Image credit: M. Huey; research credit: J. Scheingross et al.; via EOS News; submitted by Kam-Yung Soh)

Water Impacts
In the clean and simplified world of the laboratory, a droplet’s impact on water is symmetric. From a central point of impact, it sends out a ring of ripples, or even a crown splash, if it has enough momentum. But the real world is rarely so simple.
Here we see how droplets impact when the wind is blowing against them. The drops fall at an angle, creating an oblique cavity. Rings of ripples spread from the impact, but the ligaments of a splash crown form only on the leeward side. As the wind speed increases, so does the violence of the impact, eventually beginning to trap tiny pockets of air beneath the surface. Those miniature bubbles can spray droplets and aerosols into the air when they finally pop. (Image and video credit: A. Wang et al.)

Rogue Waves
After centuries of tales from sailors, in 1995 the Draupner off-shore platform recorded the first ever evidence of a freak wave – a single, wall-like wave steeper and taller than any other waves around it. Theories have been tossed back and forth for the last quarter century as to how the Draupner wave formed, but now a group of researchers report they have recreated a lab-scale version of this is famous wave.
They did so in a wave pool by making two smaller groups of waves cross one another at about 120 degrees (top). The interaction of those wave packets generated a much larger, steeper wave (bottom image sequence) that matched the profile of the Draupner wave. Recreating this past freak wave confirms that wave-crossing can lead to freak waves, which will hopefully help us forecast when conditions may be right for more to occur. (Image credit and research credit: M. McAllister et al., source; via Motherboard; submitted by Kam-Yung Soh)

Moving Droplets
Microfluidic devices – such as those used by individuals with diabetes to monitor their blood glucose levels – are all about transport. Typically, these devices use some kind of externally applied force, like a temperature gradient or electrical field, to force liquids through the device’s narrow channels. But a new study describes a way to move droplets without an external force.
The researchers built their devices using two slips of glass, coated with an oil-attracting, water-repellent mixture. They attached the glass slips with a narrow spacer at one end, leaving the other end free. This made a narrow, but slightly flexible gap. When the scientists placed an oil drop inside the closed end, it spread on the glass, pulling the two sides closer to one another. Water drops, on the other hand, tried to force the walls apart, in an effort to minimize contact. Both sets of drops, interestingly, moved toward the open end of the device.
The researchers found that the shapes assumed by the droplets create an internal pressure gradient, which, in both cases, slowly moves the drops. They call this method bendotaxis, a type of self-propulsion driven by the drops’ ability to bend the material they’re touching. It’s not a fast way to transport fluids – the drops moved only a few micrometers per second – but it may be useful for applications like drug deliveries where the liquid needs to be administered slowly over a longer period. (Image credit: TesaPhotography; research credit: A. Bradley et al.; via APS Physics; submitted by Kam-Yung Soh)

Freezing Drop Impact
At the altitudes where aircraft fly, it’s often cold enough for water drops to freeze in seconds or less. Once attached to a wing, such frozen drops disrupt the flow, reducing lift and increasing drag. To help understand how such droplets freeze, scientists study droplet impact on cold surfaces. Starting at room temperature (counter-clockwise from upper left), a drop will spread on the surface, then retract. When the temperature is colder, parts of the droplet freeze before retraction completes, leaving a thin sheet with a thicker center. At even colder temperatures, the droplet’s rim destabilizes and freezing occurs before the droplet has time to retract fully. And at the coldest temperatures, the droplet breaks apart into a frozen splash. (Image and video credits: V. Thievenaz et al.)

Putting a Spin on Splashes
Researchers put a spin on splashing droplets with selective wetting. When a drop impacts on a water-repellent, superhydrophobic surface, it will spread circularly, then pull back together and rebound off the surface. That’s because the surface coating resists actually touching – or being wetted by – the water. But just as there are surface coatings that resist water, there are those that attract it.
Above, researchers have coated a surface so that it’s mostly superhydrophobic, but it also has narrow pinwheel-like arms that are hydrophilic. As the drop impacts, it spreads across the surface and then retracts. But where the hydrophilic arms are, the drop lingers. This creates the four lobes we see on the droplet, and the asymmetric retraction gives the drop angular momentum. As it leaves the surface, the spin continues. In some configurations, the researchers could make the drop spin at more than 7300 rpm. (Image and research credit: H. Li et al; via Science; submitted by Kam-Yung Soh)

Catching Prey
The skinny, freshwater alligator gar can grow to more than 2 meters in length, giving it a distinct resemblance to its namesake. But this fish’s history traces back more than a hundred million years to the Early Cretaceous. And a new (pre-printed) study, combining live observations and numerical models built from CT-scans, is shedding new light on how the gar and its prehistoric ancestors feed.
The gar uses a lateral strike (top) to come at its prey from the side. But hydrodynamically speaking, that’s a tough way to catch dinner. As soon as the gar’s snout accelerates toward its prey, it pushes a bow wave ahead of it, like an early warning signal. To counter that disadvantage, the gar has a complex bone structure in its skull (bottom) that helps it generate suction. Note how the gar’s jaw and throat open sequentially from front to back. Each expansion sucks in water, and by timing them just right, the gar produces suction throughout its entire attack. The bow wave warning does its prey no good if both are already getting sucked into the gar’s mouth! (Image and research credit: J. Lemberg et al., bioRxiv pre-print; via Science; submitted by Kam-Yung Soh)


















