A horizontal filament of viscous liquid hanging between two plates stretches under gravity. The photo above is a composite showing the stretching of a single thread over several time steps. The fluid forms a catenary, the same shape as a hanging chain or cable when supported only at its ends. This behavior is confined to viscous filaments of sufficient length and diameter. Short and thin filaments instead form a U-shape with a thin horizontal filament joined to two thicker vertical threads. This difference in shape occurs due to the drainage of the liquid along the filament’s length. If the viscous thread begins to fall before surface tension drains the fluid from the center toward the ends, then a catenary of essentially uniform diameter forms. If instead the liquid drains before falling, the non-uniform U-shape is observed. (Photo credit: M. Le Merrer et al.)
Tag: surface tension
The Colors of Soap
The brilliant and beautiful colors of a bubble are directly related the the thickness of the soap film surrounding it. When light shines on the soap film, some rays are reflected from the upper surface of the film, while others are refracted through the film and reflect off its lower surface. These reflected rays have different phase shifts and their interference is what causes the colors we observe. The color patterns themselves reveal the interior flow of the soap film, in which gravity tries to thin the film and surface tension tries to distribute the film evenly. (Photo credit: R. Kelly, A. Fish, D. Schwichtenberg, N. Travers, G. Seese)
Stretching to Break
Have you ever wondered what happens inside a jet of fluid as it breaks into droplets? Such events are not commonly or readily measured. This video uses a double emulsion–in which immiscible fluids are encapsulated into a multi-layer droplet–to demonstrate interior fluid flow during the Plateau-Rayleigh instability. The innermost drops and the fluid encapsulating them have a low surface tension between them, thanks to the addition of a surfactant to the inner drops. As a result, the inner drops are easily deformed by motion in the fluid surrounding them. Flow on the left side of the jet is clearly parabolic, similar to pipe flow. Closer to the pinch-off, the inner droplets shift to vertical lines, indicating that the interior flow’s velocity is constant across the jet. After pinch-off, the inner droplets return to a spherical shape because they are no longer being deformed by fluid movement around them. The coiling of the inner drops inside the bigger one is due to the electrical charges in the surfactant used. (Video credit: L. L. A. Adams and D. A. Weitz)
Bubbles, Drops, and Colors
The immiscibility of oil and water creates a multitude of bubbles of all sizes. A lack of miscibility occurs when the forces between like molecules are very strong for two liquids–essentially the oil molecules and the water molecules are so much more strongly attracted to themselves than they are to one another that they cannot mix. Surface tension–another expression of molecular forces–pulls the oil into droplets that float in the water and refract the light in such lovely ways. (Photo credit: Vendula Adriana Kaprálová Hauznerová; via thinxblog)
Droplets Within Droplets
This video shows a multi-layered droplet, in which several droplets are formed one inside the other as an initial drop falls through a layer of oil sitting atop another liquid. When the drop falls, its potential energy gets transformed into interface energy, creating a fascinating interplay of surface tension, deformation, and miscibility between the fluids. Such self-contained multi-layered droplets, similar to multiple emulsions, could be helpful in pharmaceutical development. (Video credit: E. Lorenceau and S. Dorbolo 2004)
Droplet Bounce
This high-speed video shows the remarkable resilience of a water droplet upon impact against as a solid surface. The droplet deforms into a pancake-shape, with its center depressing almost flat before rebounding upward. The rest of the drop follows, splitting into several droplets as capillary waves dance across its surface. When one satellite drop almost escapes, the main droplet just barely comes in contact with it, the coalescence enough to tip surface tension into pulling them together instead of breaking them apart. (Video credit: K. Suh/ChemistryWorldUK)
Bubble Lenses
In this video, artist Jesse Zanzinger experiments with the lens-like refractive properties of bubbles. Though focused on the bending of light, there’s plenty here in terms of coalescence, surface tension, and miscibility. He has a similar video that includes a shot of his set-up here. (Video credit: J. Zanzinger)
Breaking into Droplets
A falling column of liquid, like the water from your faucet, will tend to break up into a series of droplets due to the Plateau-Rayleigh instability. This instability is driven by surface tension. Small variations in the radius of the column occur naturally. Where the radius shrinks, the pressure due to surface tension increases, causing liquid to flow away, which shrinks the column’s radius even further. Eventually the column pinches off and breaks into droplets. What’s especially neat is that the size of the final droplets can be predicted based on the column’s initial radius and the wavelength of its disturbances. (Video credit: BYU Splash Lab)
Electrowetting
The electrowetting effect can change the shape of a liquid droplet on a surface by applying a voltage across the surface and droplet. Surface tension is a kind of measure of the energy required to maintain a certain drop shape, and that energy can be both chemical and electrical. In the video above, the droplet maintains a small contact area naturally (with no voltage). It expands and flattens under an electrical charge. Varying the voltage will change the degree to which the droplet flattens, but only to a point. Electrowetting is used to control variable lenses and some types of electronic displays. The technology may be used to replace current generation LCDs. (Video credit: V. Arya/Duke University)
Self-Assembly via Evaporation
When working at the microscale, engineering structures like those used for drug delivery systems requires ingenuity. Since it isn’t possible to manipulate particles manually, researchers harness physical effects to do the work for them. Here a droplet filled with millions of polystyrene microparticles sits on a hydrophobic surface, which helps keep the drop’s spherical shape. As the drop evaporates, surface tension and internal flow in the drop help the microparticles self-assemble into a microscopic soccer-ball-like shape. (Video credit: A. Marin et al.; submission by A. Marin)
