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Tag: sessile drop

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    Evaporating Off Butterfly Scales

    This award-winning macro video shows scattered water droplets evaporating off a butterfly‘s wing. At first glance, it’s hard to see any motion outside of the camera’s sweep, but if you focus on one drop at a time, you’ll see them shrinking. For most of their lifetime, these tiny drops are nearly spherical; that’s due to the hydrophobic, water-shedding nature of the wing. But as the drops get smaller and less spherical, you may notice how the drop distorts the scales it adheres to. Wherever the drop touches, the wing scales are pulled up, and, when the drop is gone, the scales settle back down. This is a subtle but neat demonstration of the water’s adhesive power. (Video and image credit: J. McClellan; via Nikon Small World in Motion)

    Water droplets evaporate from the wing of a peacock butterfly.
    Water droplets evaporate from the wing of a peacock butterfly.
    Fediverse Reactions
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    Explosively Jetting

    Dropping water from a plastic pipette onto a pool of oil electrically charges the drop. Then, as it evaporates, it shrinks and concentrates the charges closer and closer. Eventually, the strength of the electrical charge overcomes surface tension, making the drop form a cone-shaped edge that jets out tiny, highly-charged microdrops. Afterward, the drop returns to its spherical shape… until shrinkage builds up the charge density again. This microjetting behavior can carry on for hours! (Video and image credit: M. Lin et al.; research preprint: M. Lin et al.)

  • Gravity Changes Droplet Shapes

    Gravity Changes Droplet Shapes

    With small droplets, gravity usually has little effect compared to surface tension. An evaporating water droplet holds its spherical shape as it evaporates. But the story is different when you add proteins to the droplet, as seen in this recent study.

    The protein-filled sessile drop starts out largely spherical, but as the drop evaporates, the concentration of proteins reaches a critical point and an elastic skin forms over the drop. From this point onward, the drop flattens.
    The protein-filled sessile drop starts out largely spherical, but as the drop evaporates, the concentration of proteins reaches a critical point and an elastic skin forms over the drop. From this point onward, the drop flattens.

    As a protein-doped droplet sitting on a surface evaporates, it starts out spherical, like its protein-free cousin. But, as the water evaporates, it leaves proteins behind, gradually increasing their concentration. Eventually, they form an elastic skin covering the drop. As water continues to evaporate, the droplet flattens.

    For a hanging droplet, the shape again starts out spherical. But as the drop's water evaporates and the proteins concentrate, it also forms an elastic skin. As the drop evaporates further, the skin wrinkles.
    For a hanging droplet, the shape again starts out spherical. But as the drop’s water evaporates and the proteins concentrate, it also forms an elastic skin. As the drop evaporates further, the skin wrinkles.

    In contrast, a hanging droplet with proteins takes on a wrinkled appearance once its elastic skin forms. The key difference, according to the model constructed by the authors, is the direction that gravity points. Despite these droplets’ small size, gravity makes a difference! (Image, video, and research credit: D. Riccobelli et al.; via APS Physics)

  • Free Contact Lines

    Free Contact Lines

    How a simple drop of water sits on a surface is a strangely complicated question. The answer depends on the droplet’s size, its chemistry, the roughness of the surface, and what kind of material it’s sitting on. Vetting the mathematical models that describe these behaviors is especially difficult since droplets often get stuck, or “pinned,” along their contact line where water, air, and surface meet.

    To get around this issue, researchers sent their experiment to the International Space Station, asking astronauts to run the tests for them. Without gravity‘s influence squishing drops, the astronauts could use much larger droplets than they could on Earth. Larger drops are less likely to get pinned by a stray surface defect, so on the space station, astronauts could place droplets on a vibrating platform and observe their contact line freely moving as the drop changed shape. Under these conditions, the experiment tested many surfaces with different wetting characteristics, thereby gathering data to test models we cannot easily confirm on Earth. (Image and research credit: J. McCraney et al.; via APS Physics)

  • Surface Jets in Coalescing Droplets

    Surface Jets in Coalescing Droplets

    What goes on when droplets merge is tough to observe, even with a high-speed camera. There are many factors at play: any momentum in the droplets, surface tension, gravity, and Marangoni forces, to name a few. A new study that simultaneously records multiple views of coalescence is shedding some light on these dynamics.

    The results are particularly interesting for droplets that are somewhat physically separated so that they only coalesce after one drop impacts near the other. In this situation, with droplets of equal surface tension, researchers observed a jet that forms after impact (Image 1) and runs along the top surface of the coalescing drops (Image 2). That location is a strong indication that the jet is created by surface tension and not other forces.

    To test that further, the researchers repeated the experiment but with droplets of unequal surface tension. They found that when the undyed droplet’s surface tension was higher (Image 3), Marangoni forces enhanced the surface jet, as one would expect for a surface-tension-driven phenomenon. But if the dyed droplet had the higher surface tension (Image 4), it was possible to completely suppress the jet’s formation. (Image, research, and submission credit: T. Sykes et al., arXiv)

  • Dissolving

    Dissolving

    It looks like the fiery edge of a star’s corona, but this photo actually shows a dissolving droplet. The droplet, shown as the lower dark region in this shadowgraph image, is a mixture of pentanol and decanol sitting in a bath of water. Pentanol is a type of alcohol that is fully miscible with decanol and is water soluble, so that it will dissolve into the surrounding water over time. Decanol, on the other hand, is immiscible with water, so that part of the droplet won’t mix with the surrounding water.

    The bright swirls along the droplet’s edge show areas with more pentanol. As the alcohol dissolves into the water, it forms a buoyant plume at the top of the droplet that rises due to pentanol’s lower density. That rising plume draws fresh water in from the sides, shown by the upper white arrows. Inside the droplet, flow moves in the opposite direction, from the top toward the outer edges. This is a result of uneven surface tension within the droplet. Scientists are interested in understanding the dynamics of these multiple component drops for applications like printing, where it’s desirable for pigments in an ink drop to be distributed evenly as the drop dries.  (Image credit: E. Dietrich et al.)

  • Pinning a Drop

    Pinning a Drop

    The shape of a droplet sitting on a surface depends, in part, on its surface tension properties but also on the nanoscale roughness of the surface. Small variations in the height and shape of the surface will change the area a drop contacts as well as the contact angle the edge of the drop makes with the surface. If the contact line between the drop and surface stays the same as a droplet evaporates into the surrounding gas or dissolves into the surrounding liquid, then we say the drop is pinned. A pinned drop’s contact angle will decrease as the drop’s volume decreases. This strains the ability of the nanoscale roughness to keep the drop’s edge pinned. As individual points of contact fail, the drop’s edge may jump inward to a new contact point. This set of discrete jumps between pinned states is called a stick-jump or stick-slip mode. (Image credit: E. Dietrich et al., source; see also: E. Dietrich et al. 2015)

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    The Droplet Slide

    One of the joys of science is the sense of discovery that can come even from looking at something seemingly simple. Take, for example, a water droplet sitting on a plate. If you slowly tilt the plate, the droplet’s shape will shift until a critical angle where it starts sliding down the plate. But what happens to two initially different droplets? As this video shows, tilting two droplets of initially different shapes and returning them to horizontal causes the droplets to assume the same shape. There’s a universal behavior at work here–like nature has a kind of reset button that makes gravity and surface tension work together such that a droplet will assume a preferred shape. For an experimentalist, it’s certainly a handy way to create repeatable experiments! (Video credit: M. Musterd et al.)