Tag: chemistry

Forming Vesicles on Titan
Scientists are still debating exactly what shifts nature from chemical and physical reactions to living cells. But vesicles — small membrane-bound pockets of fluid carrying critical molecules — are a commonly cited ingredient. Vesicles help cluster important organic molecules together, increasing their chances of combining in the ways needed for life. Now scientists are suggesting that Titan, Saturn’s moon, could form vesicles of its own.
On Earth, molecules known as amphiphiles feature a hydrophilic (water-loving) end and a hydrophobic (water-fearing) one. When dispersed in water, amphiphiles crowd at the surface, placing their hydrophilic end in the water and their hydrophobic end outward toward the air. On Titan, the Cassini mission revealed organic nitrile molecules that behave similarly with methane rather than water.
Their two-sided structure means that these molecules — like Earth’s amphiphiles — will gather at the surface of Titan’s liquids. When methane rain falls on the Titan’s seas, the impact creates aerosol droplets that slowly settle back to the liquid surface. When that happens, the droplet’s molecular monolayer and the lake’s monolayer meet, enclosing the droplet’s contents in a double-layer of molecules that prevent contact between the droplet and the lake.
Within that newly-formed vesicle, all kinds of molecules can bump shoulders, creating new opportunities for complex chemistry. (Image credit: Titan – ESA/NASA/JPL/University of Arizona, illustration – C. Mayer and C. Nixon; research credit: C. Mayer and C. Nixon; via Gizmodo)
Fediverse Reactions
August 5, 2025
Dancing Metal Droplets
Droplets of a gallium alloy are liquid at room temperature. When spiked with aluminum grains and immersed in a solution of NaOH, the droplets change shape and move in a random fashion. This video delves into the phenomenon, describing how a chemical reaction with the aluminum grains changes the local surface tension and creates Marangoni flows that make the droplets move. To get the droplet motion, you need to have the aluminum concentration just right. With too little, there’s not enough Marangoni flow. With too much, the hydrogen gas produced in the chemical reaction disrupts the droplet motion. (Video and image credit: N. Kim)
Fediverse Reactions
July 21, 2025
Penguin Poo Seeds Antarctic Clouds
Forming clouds requires more than just water vapor; every droplet in a cloud forms around a tiny aerosol particle that serves as a seed that vapor can condense onto. Without these aerosols, there are no clouds. In most regions of the world, aerosols are plentiful — produced by vegetation, dust, sea salt, and other sources. But in the Antarctic, aerosol sources are few. But a new study shows that penguins help create aerosols with their feces.
Penguin feces is ammonia-rich, and that ammonia, when combined with sulfur compounds from marine phytoplankton, triggers chemistry that releases new aerosol particles. The researchers measured ammonia carried on the wind from nearby penguin colonies and found that the birds are a large ammonia source, producing 100 to 1000 times the region’s baseline ammonia levels. In combination with another ingredient in penguin guano, the researchers found the penguins boosted aerosol production 10,000-fold. That means penguins can actually influence their environment, helping to create clouds that keep Antarctica cooler. (Image credit: H. Neufeld; research credit: M. Boyer et al.; via Eos)
Fediverse Reactions
June 17, 2025
Anti-Icing Polar Bear Fur
Despite spending their lives in and around frigid water, snow, and ice, polar bears are rarely troubled by ice building up on their fur. This natural anti-icing property is one Inuits have long taken advantage of by using polar bear fur in hunting stools and sandals. In a new study, researchers looked at just how “icephobic” polar bear fur is and what properties make it so.
The key to a polar bear’s anti-icing is sebum — a mixture of cholesterol, diacylglycerols, and fatty acids secreted from glands near each hair’s root. When sebum is present on the hair, the researchers found it takes very little force to remove ice; in contrast, fur that had been washed with a surfactant that stripped away the sebum clung to ice.
The researchers are interested in uncovering which specific chemical components of sebum impart its icephobicity. That information could enable a new generation of anti-icing treatments for aircraft and other human-made technologies; right now, many anti-icing treatments use PFAS, also known as “forever chemicals,” that have major disadvantages to human and environmental health. (Image credit: H. Mager; research credit: J. Carolan et al.; via Physics World)
Fediverse Reactions
March 11, 2025
Within a Drop
In this macro video, various chemical reactions swirl inside a single dangling droplet. Despite its tiny size, quite a lot can go on in a drop like this. Both the injection of chemicals and the chemical reactions themselves can cause the flows we see here. Surface tension variations and capillary waves on the exterior of the drop can play a role, too. Just because a flow is tiny doesn’t mean it’s simple. (Video and image credit: B. Pleyer; via Nikon Small World in Motion)
Chemical reactions swirl within a single, hanging droplet.
Fediverse Reactions
January 17, 2025
Blocking Bubbles
Many industrial processes, including those producing aluminum and “green” hydrogen, use electrodes to speed up chemical reactions. Unfortunately, bubbles that form on the electrode reduce its efficiency anywhere from 10 to 25 percent by blocking parts of the electrode. The assumption has been that any area shadowed by bubbles is blocked, but a recent study shows that’s not the case. Instead, it’s only the electrode area in direct contact with the bubble that’s blocked.
To show this, researchers looked at a smooth electrode where bubbles formed randomly (left) and a nanotextured one with many spots where bubbles could form (right). In the animation above, bubble shadows are highlighted with circles. There are clearly more bubbles on the nanotextured electrode, but it actually performs better than the smooth electrode because the bubble contact area is smaller. (Image and research credit: J. Lake et al.; via MIT News)
November 5, 2024
How Venus Is Losing Its Water
Since Venus formed at the same time as Earth and is similar in size, scientists believe it once had the same amount of water our planet does. Today, hellish Venus has hardly any water, a fact scientists have struggled to explain completely. Most of its water was lost long ago, as incoming particles from the solar wind stripped water from the upper atmosphere; unlike Earth, Venus doesn’t enjoy the protection of a magnetic field.
But that mechanism doesn’t explain just how arid Venus is now. A new study instead suggests that Venus’s water loss is ongoing, driven by simple chemical reactions. The team found that molecules of HCO+ (an ion made from one hydrogen, one carbon, and one oxygen atom) could mix with any remaining water to form a positively-charged molecule. Due to that charge, the chemical easily attracts loose electrons. Once combined, however, the resulting molecule is too energetic and breaks apart; when it does so, it releases highly-energetic hydrogen, which escapes the atmosphere into space. Without that hydrogen, water molecules can’t reform. This process of dissociative recombination could explain why the rest of Venus’s water has disappeared.
Science missions that have flown to Venus so far haven’t been equipped to measure HCO+, and the authors recommend this as a priority for future missions to our neighbor. With that data, we could confirm or disprove this mechanism for Venusian water loss. (Image credit: NASA; research credit: M. Chaffin et al.; via Gizmodo)
May 30, 2024
Weathering Spilled Oil
As long as we continue to extract and transport oil, marine oil spills will continue to be a problem. Recent work shows that spilled oil weathers differently depending on both sunlight and water temperature. When exposed to sunlight, crude oil undergoes chemical reactions that can change its makeup. Researchers studied the mechanical properties of crude oil samples kept at different temperatures in both sunlight and the dark.
They discovered that sunlight-exposed crude oil kept at a high temperature had twice the viscosity of a sample kept in the dark at the same temperature. In contrast, the high-temperature sunlit sample’s viscosity was 8 times lower than a sunlit sample kept at a lower temperature. That’s quite a large difference, and it implies that tropical oil spills may behave quite differently than Arctic ones. Cold-water spills will entrain and dissolve less than warm-water ones, so there may be more surface oil to collect at high-latitude spills. The differences in viscosity may also necessitate different spill mitigation techniques. (Image credit: NOAA; research credit: D. Freeman et al.; via APS Physics)
September 26, 2023
“aBiogenesis”
Many theories posit the physical and chemical origins of life. In the short film “aBiogenesis”, CGI artist Markos Kay imagines one such theory — the lipid world theory — in which cellular life began as a soup contained within immiscible fatty membranes. Chemicals trapped within these vesicles interacted and ultimately formed the building blocks of life as we know it, including RNA. Kay’s interpretation is a beautiful exploration of this intersection of physics, chemistry, and biology. (Image and video credit: M. Kay; via Colossal)
January 27, 2023
Chemical Flowers
These “flowers” blossom as two injected chemicals react in the narrow space between two transparent plates. The chemical reaction produces a darker ring that develops a streaky outer edge due to competition between convection and chemical diffusion.
To show how gravity affects the instability, the researchers repeated the experiment on a parabolic flight. In microgravity conditions, no instability formed. That’s exactly what we’d expect if convection (i.e. flow due to density differences) is a major cause. No gravity = no convection. In contrast, under hypergravity conditions, the instability was initially spotty before developing streaks. (Image and video credit: Y. Stergiou et al.)
November 7, 2022