In the ocean, waves often curl over and trap air, becoming plunging breakers. How do surfactants like soap or oil affect this process? That’s the question behind this video, where researchers visualize breaking waves with differing amounts of added surfactant. In the case of pure water, the wave forms a smooth jet that curls over and traps air when the wave breaks. As more and more surfactant gets added, the shape of that jet and cavity change. In one case, they become irregular. In another, they disappear entirely, and with the most surfactant added, the wave suddenly looks just like the water-only case.
The key to these behaviors, it turns out, is not how much surfactant there is, but how much the concentration of surfactant varies along the length of the wave. When there are significant changes in the surfactant concentration along the wave, local Marangoni flows try to even out the surface tension, causing the wave to break up in an irregular fashion. (Image and video credit: M. Erinin et al.)