Water is an endlessly peculiar substance, eager to adopt many configurations. Each molecule can form up to four, highly-directional bonds. In this study, researchers found an unexpected configuration, a 2D type of ice known as bilayer hexagonal ice, on a corrugated gold surface. Bilayer hexagonal ice has been known since the late 1990s, but it was thought to be comparatively rare. In this form, water molecules assemble in an ice only two molecular layers thick, with hydrogen bonds between neighboring molecules taking up nearly all possible binding sites. With nowhere to bind, additional water cannot add to the ice’s thickness, making the ice as a whole hydrophobic or “water-fearing”.
Previously, this type of ice had only been found on hydrophobic, flat surfaces. In the latest research, though, researchers found that surface corrugations allowed the ice to form, even on a surface that was only slightly hydrophobic. Observations like these help theorists modeling water and its interactions with surface. (Image credit: top – E. McKenna, illustration – APS/A. Stonebraker; research credit: P. Yang et. al.; via APS Physics; submitted by Kam-Yung Soh)