FYFD

Tag: surfactant

  • Featured Video Play Icon

    What Keeps a Foam Intact

    Beer, soda, soap, meringue – foams are everywhere in our lives. But have you ever wondered why some foams disappear so quickly while whipped egg whites stick around? That’s the subject of this Gastrofisica video, which is in Spanish but has English captions.

    Foams form when air gets introduced into a liquid, but for those bubbles to stick around, they need a certain special something. With soapy water, that ingredient is surfactants, molecules with both hydrophobic (water-fearing) and hydrophilic (water-loving) ends, which line up at the interface of the foam and help hold it together. But surfactants are relatively weak, especially compared to to the albumin proteins in an egg white. By whipping egg whites, you’re effectively untangling those proteins, and, like surfactants, they line up at the interface of the foam so that their hydrophobic and hydrophilic parts can hang out in their preferred mediums. With so many similar molecules crowded together, the proteins coagulate, adding extra strength and stiffness to your whipped egg whites. (Video and image credit: Tippe Top Physics; h/t to MinutePhysics)

  • Featured Video Play Icon

    Swimming Microdroplets

    Simple systems can sometimes have surprisingly complex behaviors. In this video, the Lutetium Project outlines a scheme for swimming microdroplets. Most of the droplets shown are just water, but they’re released into a chamber filled with a mixture of oil and surfactants. All flow through the chamber is shut off, but the droplets swim around in complicated, disordered patterns anyway. To see why, we have to zoom way in. The surfactant molecules in the oil cluster around the droplets, orienting so that their hydrophobic parts are in the oil and their hydrophilic parts point toward the water. They actually draw some of the water out of the droplets. This creates a variation in surface tension that causes Marangoni flow, making the droplets swim. Over time, the droplets shrink and slow down as the surfactants pull away more and more of their water and the variations in surface tension get smaller. (Image and video credit: The Lutetium Project; research credit: Z. Izri et al.)

  • Featured Video Play Icon

    Solving Mazes

    Earlier this fall, I attempted my first corn maze. It didn’t work out very well. Early on I unknowingly cut through an area meant to be impassable and thus ended up missing the majority of the maze. Soap, as it turns out, is a much better maze-solver, taking nary a false turn as it heads inexorably to the exit. The secret to soap’s maze-solving prowess is the Marangoni effect.

    Soap has a lower surface tension than the milk that makes up the maze, which causes an imbalance in the forces at the surface of the liquid. That imbalance causes a flow in the direction of higher surface tension; in other words, it tends to pull the soap molecules in the direction of the highest milk concentration. But that explains why the soap moves, not how it knows the right path to take. It turns out that there’s another factor at work. Balancing gravitational forces and surface tension forces shows that the soap tends to spread toward the path with the largest surface area ahead. That’s the maze exit, so Marangoni forces pull the soap right to the way out! (Video credit: F. Temprano-Coleto et al.; research credit: F. Peaudecerf et al.)

    ETA: Based on the latest research results, gravity may play less of a role than originally thought. Instead, it seems as though the soap chooses its path in part through pre-existing background levels of surfactant. As the dye advances, it compresses the background surfactant, decreasing the local surface tension until it is in equilibrium with dyed area. Because longer paths take longer to reach that equilibrium, the dye spreads preferentially toward the largest surface area.

  • Detergency

    Detergency

    Have you ever wondered just how detergents are able to get grease and oil off a surface? This simple example demonstrates one method. In the top image, a drop of oil sits attached to a solid surface; both are immersed in water. An eyedropper injects a surfactant chemical near the oil drop. This lowers the surface tension of the surrounding water and allows the mixture to better wet the solid. That eats away at the oil drop’s contact with the surface. It takes awhile – the middle animation is drastically sped up – but the oil droplet maintains less and less contact with the surface as the surfactant works. Eventually, in the bottom image, most of the oil drop detaches from the surface and floats away.   (Image credits: C. Kalelkar and A. Sahni, source)

  • Self-Healing Bubbles

    Self-Healing Bubbles

    Soap films have the remarkable property of self-healing. A water drop, like the one shown above, can pass through a bubble (repeatedly!) without popping it. This happens thanks to surfactants and the Marangoni effect. Surfactants are molecules that lower the surface tension of a liquid and congregate along the outermost layer of a soap film. When water breaks through the soap film, its lack of surfactants causes a higher surface tension locally. This triggers the Marangoni effect, in which flow moves from areas of low surface tension toward ones of high surface tension. That carries surfactants to the region where the drop broke through and helps stabilize and heal the soap film. Incidentally, the same process lets you stick your finger into a bubble without popping it as long as your hand is wet! (Image credit: G. Mitchell and P. Taylor, source)

  • Stabilizing Films

    Stabilizing Films

    Liquids don’t typically survive very long as thin films. If you try to make one from water, gravity drains it away immediately. (Not so in space.) To make a liquid film stick around, we add surfactants like soap. These extra molecules congregate at the surface of the film and provide a stabilizing force to oppose gravity’s drainage. Exactly what that stabilizing force is depends on the surfactant.

    Surfactants that are insoluble are often quite viscous. These molecules distribute themselves across the interface and then they stay. They resist both gravity or even just moving thanks to their high viscosity. That produces a soap film pattern like the one on the right – symmetric and slow to change.

    Other surfactants may be soluble in the film and have no appreciable viscosity themselves. These surfactants constantly move and shift on the interface as surface tension variations occur. When weak spots form, the surfactant molecules shift, via the Marangoni effect, to stabilize the film. This creates a film pattern like the familiar one on the right, with an ever-shifting palette of colors. (Image and research credit: S. Bhamla et al., source; submission by S. Bhamla)

  • The Coalescence Cascade and Surfactants

    The Coalescence Cascade and Surfactants

    Drops of a liquid can often join a pool gradually through a process known as the coalescence cascade (top left). In this process, a drop sits atop a pool, separated by a thin air layer. Once that air drains out, contact is made and part of the drop coalesces. Then a smaller daughter droplet rebounds and the process repeats.

    A recent study describes a related phenomenon (top right) in which the coalescence cascade is drastically sped up through the use of surfactants. The normal cascade depends strongly on the amount of time it takes for the air layer between the drop and pool to drain. By making the pool a liquid with a much greater surface tension value than the drop, the researchers sped up the air layer’s drainage. The mismatch in surface tension between the drop and pool creates an outward flow on the surface (below) due to the Marangoni effect. As the pool’s liquid moves outward, it drags air with it, thereby draining the separating layer more quickly. The result is still a coalescence cascade but one in which the later stages have no rebound and coalesce quickly. (Image and research credit: S. Shim and H. Stone, source)

    image
  • Reducing Drag with Bubbles

    Reducing Drag with Bubbles

    Large ships experience a great deal of drag due to friction between their hull and the water. One method shipbuilders are considering to combat this drag is the use of bubbles, which have been found to reduce drag by up to 40%. The physical mechanism behind this drag reduction is not yet understood, but a recent study suggests that bubble size and bubble coalescence play an important role.

    Researchers introduced surfactants into bubbly boundary layers and found that the reductions in drag evaporated as soon as the surfactants spread. Adding only 6 parts per million of the surfactant decreased average bubble size from 1 mm to 0.1 mm and helped prevent the bubbles from growing via coalescence. The implications are that bubble-induced drag reduction could be extremely sensitive to water conditions. (Image credit: G. Kiss; research credit: R. Verschoof et al.)

  • Supporting Bubbles

    Supporting Bubbles

    Surface tension holds small droplets in a partial sphere known as a spherical cap. But when droplets become larger, they flatten out into puddles due to the influence of gravity. In contrast, soap bubbles remain spherical to much larger sizes. The bubble pictured above, for example, is more than 1 meter in radius and nearly 1 meter in height.

    There is a maximum height for a soap bubble, though, and it’s set by the physical chemistry of the surfactants used in the soap. To support itself, the bubble requires a difference in surface tension between the top and bottom of the bubble. A higher surface tension is necessary at the top of the bubble to help prevent fluid from draining away. The difference in surface tension between the top and bottom of the bubble can never be greater than the difference in surface tension between pure water and the soap mixture – thus those values set a maximum height for a bubble. The researchers found their bubbles maxed out at a height of about 2 meters, consistent with their theoretical predictions. (Image credit: C. Cohen et al.; via freshphotons)

  • Featured Video Play Icon

    Soap Film Turbulence

    The brilliant colors of a soap film reveal the fluid’s thickness, thanks to a process known as thin film interference. The twisting flow of the film depends on many influences: gravity pulls down on the liquid and tends to make it drain away; evaporation steals fluid from the film; local air currents can push or pull the film; and the variation in the concentration of molecules – specifically the surfactants that stabilize the film – will change the local surface tension, causing flow via the Marangoni effect. Together these and other effects create the dancing turbulence captured above. (Video credit: A. Filipowicz)