Tag: miscibility

Bubbles, Drops, and Colors
The immiscibility of oil and water creates a multitude of bubbles of all sizes. A lack of miscibility occurs when the forces between like molecules are very strong for two liquids–essentially the oil molecules and the water molecules are so much more strongly attracted to themselves than they are to one another that they cannot mix. Surface tension–another expression of molecular forces–pulls the oil into droplets that float in the water and refract the light in such lovely ways. (Photo credit: Vendula Adriana Kaprálová Hauznerová; via thinxblog)
June 14, 2013
Droplets Within Droplets
This video shows a multi-layered droplet, in which several droplets are formed one inside the other as an initial drop falls through a layer of oil sitting atop another liquid. When the drop falls, its potential energy gets transformed into interface energy, creating a fascinating interplay of surface tension, deformation, and miscibility between the fluids. Such self-contained multi-layered droplets, similar to multiple emulsions, could be helpful in pharmaceutical development. (Video credit: E. Lorenceau and S. Dorbolo 2004)
June 6, 2013
Bubble Lenses
In this video, artist Jesse Zanzinger experiments with the lens-like refractive properties of bubbles. Though focused on the bending of light, there’s plenty here in terms of coalescence, surface tension, and miscibility. He has a similar video that includes a shot of his set-up here. (Video credit: J. Zanzinger)
May 27, 2013
Encapsulating Droplets
In applications like drug delivery, it’s often desirable to encapsulate one or more liquid droplets in an additional immiscible fluid. These drops-within-drops, called double emulsions, are typically a multi-step process, created from the innermost drop outward. In this new microfluidic technique, though, researchers are able to create multi-component emulsions in a single step. A double-bored capillary tube creates the two inner droplets (both water, dyed different colors) while oil flows down the outside of the injection tube to encapsulate the droplets. The multi-component double emulsions then flow as one to the right in the outer carrier fluid. The spacing of the capillary tubes is critical to prevent the inner droplets from coalescing with one another. (Video credit: L. L. A. Adams et al.)
May 9, 2013
Bouncing to Mix Oil and Water
Mixing immiscible liquids–like oil and water–is tough. The best one can usually do is create an emulsion, in which droplets of one fluid are suspended in another. The series of images above shows a double emulsion consisting of oil and water that’s been formed by bouncing the compound droplet on a vibrating bath. The vibration of the liquid surface keeps the droplet from coalescing with the bath and the deformation provides mixing. The top row shows the initial impact while the bottom row of images shows the droplet after many bounces. As time goes on, the layer of oil around the compound drop becomes a cluster of tiny droplets contained within the water portion of the drop. (Photo credit: D. Terwagne et al.)
April 11, 2013
Bubbles and Jets
In the photo sequence above, a bubble is created at the interface between two immiscible liquids–water on top and denser hydrofluroether (HFE) below. Initially, the bubble expands explosively due to the vaporization of water generated by a short laser pulse. As the bubble collapses, a jet forms and accelerates into the HFE. After collapse, the bubble remnants injected in the HFE cause the formation of a jet that shoots back into the water above. Surface instabilities make the jet assume a mushroom or crown-like structure that detaches from the jet. Eventually gravity will return the system to its initial undisturbed fluid-fluid interface. (Photo credit: S. Avila et al. 1,2)
August 24, 2012
Oil in Alcohol
In this video two droplets of oil fall through a bath of isopropyl alcohol. The oil is denser than alcohol, and the two fluids are miscible. The velocity and density gradients where the two fluids meet generate hydrodynamic instabilities that create the distinctive patterns seen in the falling drops. (Video credit: BYU Splash Lab)
July 26, 2012
Making Mixed Emulsions
Ever tried to mix oil and vinegar? Anyone who has ever dealt with salad dressings knows the difficulty of evenly distributing immiscible fluids; the key is to shake them and create an emulsion, where droplets of one fluid are distributed throughout another. In this video, researchers create a double emulsion–oil in water in oil–without touching the two fluids. First they suspend a drop of water on a wire and then coat it with oil. Below, they place a bath of silicone oil, which they vibrate. When the oil-coated droplet falls onto the bath, it bounces on the surface rather than coalescing because a thin layer of air–constantly refreshed due to the vibration of the surface–separates the droplet from the bath. When the amplitude of the vibration is large enough, the oil coating penetrates the water during the bounce, leaving behind a tiny droplet and creating the emulsion. (Video credit: D. Terwange et al; Research paper)
February 16, 2012
Underwater Plumes
During 2010’s Deepwater Horizon oil spill there were reports of underwater plumes of oil escaping collection. This video demonstrates how such a plume can form. There are two clips shown here; in both the tank is filled with salt water of varying salinity, with denser saltwater at the bottom. The first jet is a green alcohol/water mixture and the second is a red gauge oil. Both jets have the same density and flow rate, but they vary in their Reynolds number. The first turbulent jet gets trapped at the interface between the denser and lighter saltwater while the less turbulent red jet passes the interface with no difficulty. The researchers suggest that strong turbulence can create an emulsion, a mixture of two normally immiscible fluids–imagine shaking a container of oil and vinegar really well–which can lead to underwater trapping.
December 7, 2011
“Oil in Water”
There’s beauty even in something as simple as two immiscible fluids–oil and water–colliding. (Video credit: Shawn Knol)
November 17, 2011