Research

Drying Unaffected by Humidity

Microscope image of the gel layer that forms at the interface between air and a polymer solution. Beneath the gel lies a viscoelastic layer of concentrated polymers.

Water evaporates faster in dry conditions than in humid ones, but the same isn’t true of paint. Instead, paint’s drying time is largely independent of the day’s humidity. That’s because of paint’s long chains of polymers. As water in the paint evaporates, these polymers are drawn to the surface, forming a viscoelastic layer that hinders evaporation and keeps the drying rate independent up to about 80 percent humidity.

Illustration depicting evaporation of water (left) and evaporation of a polymer solution (right). As water evaporates from the polymer solution, it draws polymers to the surface, where they form a layer that hinders evaporation and makes its rate independent of humidity.
Illustration depicting evaporation of water (left) and evaporation of a polymer solution (right). As water evaporates from the polymer solution, it draws polymers to the surface, where they form a layer that hinders evaporation and makes its rate independent of humidity.

The polymer layer explains why evaporation isn’t affected by humidity at longer times, but researchers also saw humidity-independent evaporation early in their experiments. Under a microscope, they discovered a thin gel layer (top image) covering the air-polymer interface. They propose that this fast-forming layer further hinders evaporation. Their findings may be significant for virus-laden respiratory droplets, which also contain polymers. (Image and research credit: M. Huisman et al.; see also J. Salmon et al.; via APS Physics)

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