Tag: sublimation

Zen Stones
On Lake Baikal, where Siberian winters are long and cold but have little precipitation, you can find a strange phenomenon: stones that balance on a thin spire of ice. Known as Zen stones — thanks to their visual similarity to stacks of balanced stones in Japanese Zen gardens — these natural oddities rely on time and sublimation, a transition from ice to vapor without melting.
The process is simple. Toss a stone on the ice and wait. As the sun shines, the ice will sublimate, transforming from ice directly to vapor at an estimated rate of ~2 mm per day, for Lake Baikal’s typical weather. But the stone’s presence acts like an umbrella, protecting some of the ice beneath it from the sunlight that is critical for sublimation. As a result of this umbrella effect, a thin column of ice remains beneath the stone.
In the lab, researchers were able to recreate the process in less time by tweaking the temperature, humidity, and irradiance to enhance sublimation. Instead of stones, they used metal disks, but their Zen stones made their ice columns just the same. (Image and research credit: N. Taberlet and N. Plihon; via Physics Today)
A lab Zen stone, formed from a disk of aluminum atop a column of ice.
October 11, 2022
Freezing Stains
When they evaporate, drops of liquids like coffee and red wine leave behind stains with a darker ring along the edges, thanks to capillary action and surface tension pulling particles to that outer edge. In contrast, sublimating a frozen droplet leaves a stain pattern that concentrates at the center (top). When droplets freeze from the surface upward, particles within the droplet are driven toward the center as the freeze front pushes toward the drop apex. The final shape of the stain depends on the initial geometry of the droplet, and the concentration of particles toward the center occurs because of the way that the particle freezes, not how it sublimates (bottom).
Since many industrial processes rely on droplet evaporation to spread coatings, this work offers a new way to control the final outcome. (Image and research credit: E. Jambon-Puillet, source)
April 26, 2019
Icy Penitentes
At high, dry altitudes, fields of snow transform into rows of narrow, blade-like formations as tall as 2 meters. Known as penitentes – due to their similarity to kneeling worshipers – these surreal snow sculptures form primarily due to solar reflection. Surrounded by dry air and intense sunlight, the snow tends to sublimate directly into water vapor rather than melt into water. This turns an initially flat snowfield into one randomly dotted with little depressions. The curved surface of those depressions helps reflect incoming sunlight, causing the indentations to grow deeper and deeper over time. Although the high Andes are best known for their penitentes, they form elsewhere as well. Recent work has even identified them on Pluto! (Image credit: G. Hüdepohl; research credit: M. Betterton)
September 6, 2018
Leidenfrost Atop Gasoline
The animations above show a little of what happens when you pour a spoonful of liquid nitrogen onto a container of gasoline. A couple of things are happening simultaneously here. First of all, the liquid nitrogen is experiencing the Leidenfrost effect. Because of the extreme difference in temperature between the gasoline (~20 degrees C) and the liquid nitrogen (-196 degrees C), part of the nitrogen is evaporating immediately, creating a vapor layer that insulates the remainder of the liquid nitrogen and allows it to float above the gasoline surface. The same thing happens to water drops on a very hot skillet.
The extreme cold of the nitrogen also seems to have formed some ice that’s further protecting the nitrogen drop. I’m not 100% sure what that would be made of, though – a mixture of water and gasoline?
Finally, there’s the simultaneous evaporation of the liquid nitrogen and the sublimation of the ice. This is the white vapor we see propelling and spinning the ice/drop. Note the “bounce” that happens in the top animation. The drop never actually impacts the wall. When it gets close, the escaping vapors are affected by the wall and start pushing the drop in a new direction! Check out the whole video below. (Image credit: carsandwater; via Gizmodo)
August 31, 2016
Sublimation
Sublimation is a transition directly from a solid phase to a gaseous one. Given typical Earth atmospheric conditions, one of the most commonly observed examples of sublimation is that of solid carbon dioxide, a.k.a. dry ice. Submerging dry ice in water both speeds up the sublimation–since water is a better conductor of heat than air–and creates ethereal fog that’s a combination of the expanding carbon dioxide and condensate from the water. This gorgeous video from Wryfield Lab lets you admire the process close-up. As the dry ice sublimates, watch for the ice crystals that grow on its surface. This is deposition–the opposite of sublimation–and comes from water vapor freezing onto the dry ice. (Video credit: Wryfield Lab; via Gizmodo)
A warning for those who want to try this at home: only do this in well-ventilated spaces. The shift from solid to gas requires a huge increase in volume. Carbon dioxide is denser than air, so it does stay low to the ground, but you can still suffocate yourself (or children or pets) if you do this in an enclosed space.
June 27, 2016
Pouring Molten Aluminum on Dry Ice
What happens when you pour molten aluminum on dry ice? As the Backyard Scientist shows, you get what looks like slippery, sliding, boiling metal. In fact, what you see may remind you of the Leidenfrost effect, where a liquid can slide around over an extremely hot surface on a thin film of its own vapor. Despite the opposite temperature extremes–this is a very cold surface rather than a very hot one–a very similar thing is happening here. The molten aluminum is so much hotter than the dry ice that it causes the dry ice to sublimate, releasing gaseous carbon dioxide that the aluminum slides around on. For the same reason, the aluminum appears to boil in the bottom animation. What we’re really seeing is carbon dioxide gas rising and escaping the aluminum so violently that it carries some of the metal with it. Be sure to check out the full video for more awesome physics! (Image credit: The Backyard Scientist, source; via Gizmodo)
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January 29, 2016
Rebounding Off Dry Ice
Droplet rebound is frequently associated with superhydrophobic surfaces but can also be generated by very large temperature differences. For very hot substrates, a thin layer of the drop vaporizes on contact via the Leidenfrost effect and helps a drop rebound by preventing it from wetting the surface. This video shows almost the opposite: a water droplet hitting solid carbon dioxide (-79 degrees C). Upon contact, the solid carbon dioxide sublimates, creating a thin layer of gas that separates the droplet from the surface. You can also see the vortex ring that accompanies the drop’s impact. Water vapor near the carbon dioxide surface has condensed into tiny airborne droplets that act as tracer particles that reveal the vortex’s formation and the rebounding droplet’s wake. (Video credit: C. Antonini et al.; Research paper)
August 13, 2013