In the image above we see two spheres of the same size, shape, and material being dropped into water. The left sphere has almost no splash, whereas the one on the right has a spectacular curtain-like splash. Why the big difference? It all comes down to the surface treatments. The glass sphere on the left is hydrophilic, but the right one has been treated to be hydrophobic. As a result, the water-fearing molecules of that sphere push the water away, allowing air to be entrained below the water’s surface instead. This creates a big splash that’s absent when the water moves smoothly around the hydrophilic sphere. (Photo credit: L. Bocquet et al.)
Tag: superhydrophobic
Hydrophobia
Hydrophobic literally means water-fearing, and, once a surface is treated with a hydrophobic coating, the effect on water droplets is stark. The tendency of the non-polar hydrophobic molecules to repel the polar water molecules leads to high contact angles – which make the droplets almost spherical as they glide along the surface. The droplets dance across the surface, colliding and bouncing and coalescing. (Video and submission credit: M. Bell)
Self-Assembly via Evaporation
When working at the microscale, engineering structures like those used for drug delivery systems requires ingenuity. Since it isn’t possible to manipulate particles manually, researchers harness physical effects to do the work for them. Here a droplet filled with millions of polystyrene microparticles sits on a hydrophobic surface, which helps keep the drop’s spherical shape. As the drop evaporates, surface tension and internal flow in the drop help the microparticles self-assemble into a microscopic soccer-ball-like shape. (Video credit: A. Marin et al.; submission by A. Marin)
Evaporation and Surface Effects
Surface properties can have surprising effects on fluid behavior. This image shows the evaporation of several droplets over time. All of the initial droplets are of the same volume, but they are placed on a surface which is a) superhydrophobic, b) hydrophobic, or c) hydrophilic. The more hydrophobic the surface, the larger the initial contact angle between the droplet and surface and the smaller the wetted area of the surface. Yet despite this seemingly large surface area exposure to air, the droplet on the superhydrophobic surface is the slowest to evaporate. (Photo credit: C. Choi)
Making Metal Water-Repellent
Chemical treatments can be used to render metals hydrophobic, causing water to bead on the surface rather than spreading to wet it. Treating the surface by immersing it in boiling water before applying the chemicals creates a nanoscale texture that accentuates the hydrophobicity. Even on a common metal like aluminum, this combination of texturing and chemical treatment leads to superhydrophobic behavior. Here the technique is demonstrated by spraying water droplets on a piece of treated aluminum. (Video credit: B. Rosenberg et al.; submitted by D. Quinn)
Frozen Powder Drops
Droplet impacts on granular surfaces and water interactions with superhydrophobic surfaces are not unfamiliar topics for FYFD. But this behavior of water droplets falling on a superhydrophobic powder is unusual, to say the least. When the droplets impact in powder, they rebound with a partial coating of powder. In the case of the superhydrophobic powder, the shape of the droplet is “frozen” by the powder. A satellite droplet is ejected from the region not coated in powder and the resultant main drop falls back to the surface and comes to rest with little to no deformation. The researchers report a critical velocity at which the behavior is observed. (Video credit: J. Marston et al.; via Physics Buzz)
Boiling Without Bubbles
Water droplets sprinkled on a sufficiently hot frying pan will skitter and skate across the surface on a thin layer of vapor due to the Leidenfrost effect. When a solid object is much warmer than a liquid’s boiling temperature, the surface is surrounded by a vapor cloud until the solid cools to the point that the vapor can no longer be sustained. Then the vapor breaks down in an explosive boiling full of bubbles. Unless, as researchers have just published in Nature, the solid is treated with a superhydrophobic coating. The water-repellent surface prevents the bubbling, even as the sphere cools. The technique could be used to reduce drag in applications like the channels of a microfluidic device. (Video credit: I. Vakarelski et al.; see also Nature News; submitted by Bobby E)
Liquid Logic Gates
Researchers have built logic gates–a physical implementation of Boolean logic–using droplets on a superhydrophobic surface. The video above demonstrates their flip-flop memory gate. Incoming droplets travel on a single track, striking a stationary “memory droplet” which then goes into one of the two output tracks according to its memory state. The memory state of the droplet relies on its position; the droplet sits on an infinity-shaped depression. When the incoming droplet strikes the sitting one, the droplet will exit via the track closest to its depression. The droplet that struck it will, as a result of the momentum transfer of the collision, rebound the opposite direction into the other depression, thereby storing the opposite memory state. See here for videos demonstrating other logic gates. (Video credit: H. Mertaniemi et al.; submitted by L. Buss)
Bouncing Off
A water droplet falling onto a superhydrophobic surface will rebound and bounce without wetting the surface. Capillary and internal waves reflect in the drop until it comes to rest at a high contact angle, formed at the boundary where the liquid, solid, and air meet. Such surfaces can have interesting interactions with water, as when two droplets coalesce on a surface and then begin bouncing or when superhydrophobic objects are dropped into a bath. (Video credit: Gangopadhyay Group, University of Missouri)
Hydrophobic Water Entry
Many factors can affect the size and shape of the splash when an object impacts water and wettability–the ability of a liquid to maintain contact with a solid–is one of them. Here a sphere coated in a hydrophobic (water-repellent) nano-layer impacts water, creating a large air, streaky air cavity and a substantial splash. Contrast this with the behavior of a hydrophilic sphere entering the water, and you can imagine divers might want to invest in some hydrophilic coatings prior to the London Olympics. (Video credit: L. Bocquet et al)
