Emulsions By Condensation

Oil and water are hard to mix, as any salad dressing aficionado will attest. Technically, the two fluids are immiscible – they won’t mix with one another – but one way around this is to emulsify them by distributing droplets of one in the other. This is usually accomplished by shaking or using sound waves to vibrate the mixture, but the results are typically short-lived. The larger a droplet is, the more gravity affects it, causing the buoyant oil to rise and separate from the water.

The key to making an emulsion last is creating tiny droplets, which a new study accomplishes energy efficiently through condensation. Instead of mixing the oil and water immediately, the researchers used a surface covered in a mixture of oil and surfactant and cooled it in a humid chamber. As the temperature dropped, water condensed onto the oil and became encapsulated, creating nanoscale emulsion droplets. At such a tiny scale, buoyant forces are unable to overcome surface tension, so the emulsion remains stable for months. (Image credit: MIT, source; research credit: I. Guha et al.; via MIT News)

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